Title:
VINYLPYRIDINE RESIN FOR CATALYST CARRIERS, PRODUCTION METHOD THEREFOR, AND CATALYST FOR METHANOL CARBONYLATION REACTION
Document Type and Number:
WIPO Patent Application WO/2017/159466
Kind Code:
A1
Abstract:
Provided are: a vinylpyridine resin for catalyst carriers, which exhibits excellent heat resistance, abrasion resistance, and catalytic activity for a catalyst on which rhodium is carried; a method for producing same; and a catalyst for use in a methanol carbonylation reaction. This vinylpyridine resin has: a pyridine-derived nitrogen content of 3.00-8.00 mass%; a degree of cross-linkage of 35-70 mol%; a mole ratio C/N of 12.00-36.00 between carbon atoms and nitrogen atoms; a total pore volume of 0.20-0.45 cc/g; a specific surface area of 70.0-280 m2/g; and an average pore diameter of 5.0-25.0 nm, wherein the volume of the pores having a pore diameter of at least 10 nm accounts for 4.0-90.0% of the total pore volume.
Inventors:
HASHIMOTO CHIKAKO (JP)
KANAI RYUICHI (JP)
YOU ZHIXIONG (JP)
MATSUMURA TETSURO (JP)
UMEHARA YOICHI (JP)
KANAI RYUICHI (JP)
YOU ZHIXIONG (JP)
MATSUMURA TETSURO (JP)
UMEHARA YOICHI (JP)
Application Number:
PCT/JP2017/009057
Publication Date:
September 21, 2017
Filing Date:
March 07, 2017
Export Citation:
Assignee:
CHIYODA CORP (JP)
International Classes:
B01J31/06; B01J23/46; B01J32/00; C08F226/06; C08J9/28; C07B61/00; C07C51/12; C07C53/08; C07D213/16
Foreign References:
| JPH07309800A | 1995-11-28 | |||
| JP2012081440A | 2012-04-26 | |||
| EP2631010A1 | 2013-08-28 | |||
| JPH0892322A | 1996-04-09 | |||
| JPS473334B1 | ||||
| JPS63253047A | 1988-10-20 | |||
| JPH05306253A | 1993-11-19 | |||
| JPH05306254A | 1993-11-19 | |||
| JPH06315637A | 1994-11-15 | |||
| JPS6125731A | 1986-02-04 | |||
| JP2012081440A | 2012-04-26 |
Other References:
HAMID, M. A. ET AL.: "4-Vinylpyridine-Ethylene Glycol Dimethacrylate Copolymers. Formation of Porous Structure by Using Cyclohexanone and Toluene as Diluents in Suspension Polymerization", POLYMER JOURNAL, vol. 28, no. 12, 1996, pages 1052 - 1059, XP000637628
MAILLARD-TERRIER, M.C. ET AL.: "Texture poreuse de copolymeres 4-vinylpyridine divinylbenzene", EUROPEAN POLYMER JOURNAL, vol. 20, no. 2, 1984, pages 113 - 118, XP024056353
DE SANTA MARIA, L. C. ET AL.: "Microscopic analysis of porosity of 2-vinylpyridine copolymer networks: 1. Influence of diluent", MATERIALS LETTERS, vol. 58, no. 5, February 2004 (2004-02-01), pages 563 - 568, XP004483141
MALIK, M. A.: "Macroporous 4-Vinylpyridine- divinylbenzene - Estimation of Pore Volume Surface Area, and Pore Size Distribution", E- POLYMERS, vol. 6, no. 1, 19 July 2006 (2006-07-19), pages 1 - 8, XP002682308, ISSN: 1618-7229
See also references of EP 3431177A4
MAILLARD-TERRIER, M.C. ET AL.: "Texture poreuse de copolymeres 4-vinylpyridine divinylbenzene", EUROPEAN POLYMER JOURNAL, vol. 20, no. 2, 1984, pages 113 - 118, XP024056353
DE SANTA MARIA, L. C. ET AL.: "Microscopic analysis of porosity of 2-vinylpyridine copolymer networks: 1. Influence of diluent", MATERIALS LETTERS, vol. 58, no. 5, February 2004 (2004-02-01), pages 563 - 568, XP004483141
MALIK, M. A.: "Macroporous 4-Vinylpyridine- divinylbenzene - Estimation of Pore Volume Surface Area, and Pore Size Distribution", E- POLYMERS, vol. 6, no. 1, 19 July 2006 (2006-07-19), pages 1 - 8, XP002682308, ISSN: 1618-7229
See also references of EP 3431177A4
Attorney, Agent or Firm:
OKABE Yuzuru et al. (JP)
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