PURPOSE: To smoothly obtain the subject compound useful as e.g. an agrochemical without any scaling derived from a copper catalyst by reaction of allyl chloride with ammonia water in the presence of the copper catalyst followed by oil-water separation and adding a specific compound to the aqueous phase, and then separately distilling the aqueous phase and oily phase.
CONSTITUTION: A reaction is carried out between allyl chloride and ammonia water in the presence of cuprous chloride, and water is then added to the resultant reaction product liquor to conduct an oil-water separation; an iron compound such as ferrous chloride, ferrous sulfate or ferrous nitrate, or an aluminum compound such as aluminum chloride, aluminum sulfate, aluminum nitrate, sodium aluminate or aluminum (hydr)oxide is added to the resultant aqueous phase followed by, or under such addition, and separately distilling the aqueous phase and the oily phase to obtain the objective allylamine.
FUJII TAKEO
MATSUMOTO YASUO
UNO OSAMU
KOEI CHEMICAL CO
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