Title:
PRODUCTION OF POLY-O-HYDROXYAMIDE AND POLY-O-MERCAPTOAMIDE
Document Type and Number:
Japanese Patent JP3167630
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To economically obtain poly-o-hydroxyamide and poly-o- mercaptoamide, soluble in an aqueous alkaline developing agent not containing a metal ion by using a method not including a chloride and reacting a bis-o- amino(thio)phenol with a dicarboxylic acid derivative having a specific structure.
SOLUTION: These objective compounds are obtained by reacting (A) a bis-o-amino(thio)phenol with (B) a dicarboxylic acid derivative of formula: I {D is O, S or NH; R1, R2 are each independently H, F, CH3, CN or NO2, at least one group of R1, R2 is CN or NO2; R* is -(CR2)m [R is H, F, CH3 or CF3; (m) is 1-10], a group of formula II or III [A is C(CH3)2, C(CF3)2, C(CH3)(C6H5), C(CF3)(C6H5), etc.] or a group of formula IV (X is CH or N)} preferably in the presence of a basic catalyst (preferably a tertiary amine), preferably at 20-150°C. Further, as the component (B), the dicarboxylic acid ester having a nitrophenol group is preferably used.
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Inventors:
Lekai Zechi
Helmut Arne
FA Ritsucel
Kurt Geiber
Helmut Arne
FA Ritsucel
Kurt Geiber
Application Number:
JP24552296A
Publication Date:
May 21, 2001
Filing Date:
August 28, 1996
Export Citation:
Assignee:
Siemens Aktiengesellschaft
International Classes:
C08G69/28; C08G69/32; C08G69/26; C08G73/22; C08G75/32; G03F7/037; G03F7/038; (IPC1-7): C08G69/26; G03F7/037
Other References:
ＣＨＥＭＩＣＡＬ ＡＢＳＴＲＡＣＴＳ，ｖｏｌ．１０５，ｎｏ．２４，１５ Ｄｅｃｅｍｂｅｒ １９８６（１９８６−１２−１５）；ａｂｓｔｒａｃｔ ｎｏ．２０９４８４，Ｋａｒｔｖｅｌｉｓｈｖｉｌｉ，Ｔ．Ｍ． ＥＴ．ＡＬ．；”Ａ ｓｉｄｅ ｒｅａｃｔｉｏｎ ｉｎ ａｃｔｉｖａｔｅｄ ｐｏｌｙｃｏｎｄｅｎｓａｔｉｏｎ”ｐａｇｅ ６
ＣＨＥＭＩＣＡＬ ＡＢＳＴＲＡＣＴＳ，ｖｏｌ．１０７，ｎｏ．２４，１４ Ｄｅｃｅｍｂｅｒ １９８７（１９８７−１２−１４）；ａｂｓｔｒａｃｔ ｎｏ．２１８１６５ｇ，Ａｖａｌｉｓｈｖｉｌｉ，Ｌ．Ｍ．ＥＴ ＡＬ．；”Ｒｕｌｅｓ ｏｆ ｐｏｌｙｃｏｎｄｅｎｓａｔｉｏｎ ｏｆ ａｃｔｉｖｅ ｄｉｅｓｔｅｒｓ ｗｉｔｈ ｄｉａｍｉｎｅｓ．Ｅｆｆｅｃｔ ｏｆ ｔｈｅ ｎａｔｕｒｅ ｏｆ ｔｈｅ ｌｅａｖｉｎｇ ｇｒｏｕｐｓ”ｐａｇｅ ６
ＣＨＥＭＩＣＡＬ ＡＢＳＴＲＡＣＴＳ，ｖｏｌ．１０８，ｎｏ．１６，１８ Ａｐｒｉｌ １９８８（１９８８−０４−１８）；ａｂｓｔｒａｃｔ ｎｏ．１３２３９３ｐ，Ｚａａｌｉｓｈｖｉｌｉ，Ｍ．Ｍ．ＥＴ ＡＬ．；”Ｃｈａｒａｃｔｅｒｉｓｔｉｃｓ ｏｆ ｐｏｌｙｃｏｎｄｅｎｓａｔｉｏｎ ｏｆ ａｃｔｉｃａｔｅｄ ｄｉｅｓｔｅｒｓ ｗｉｔｈ ｄｉａｍｉｎｅｓ．Ｅｆｆｅｃｔ ｏｆ ｔｈｅ ｎａｔｕｒｅ ｏｆ ｌｅａｖｉｎｇ ｇｒｏｕｐｓ ｏｎ ｐｏｌｙａｍｉｄｅｓ ｖｉｓｃｏｓｔｉｙ，”ｐａｇｅ ５
ＣＨＥＭＩＣＡＬ ＡＢＳＴＲＡＣＴＳ，ｖｏｌ．１０７，ｎｏ．２４，１４ Ｄｅｃｅｍｂｅｒ １９８７（１９８７−１２−１４）；ａｂｓｔｒａｃｔ ｎｏ．２１８１６５ｇ，Ａｖａｌｉｓｈｖｉｌｉ，Ｌ．Ｍ．ＥＴ ＡＬ．；”Ｒｕｌｅｓ ｏｆ ｐｏｌｙｃｏｎｄｅｎｓａｔｉｏｎ ｏｆ ａｃｔｉｖｅ ｄｉｅｓｔｅｒｓ ｗｉｔｈ ｄｉａｍｉｎｅｓ．Ｅｆｆｅｃｔ ｏｆ ｔｈｅ ｎａｔｕｒｅ ｏｆ ｔｈｅ ｌｅａｖｉｎｇ ｇｒｏｕｐｓ”ｐａｇｅ ６
ＣＨＥＭＩＣＡＬ ＡＢＳＴＲＡＣＴＳ，ｖｏｌ．１０８，ｎｏ．１６，１８ Ａｐｒｉｌ １９８８（１９８８−０４−１８）；ａｂｓｔｒａｃｔ ｎｏ．１３２３９３ｐ，Ｚａａｌｉｓｈｖｉｌｉ，Ｍ．Ｍ．ＥＴ ＡＬ．；”Ｃｈａｒａｃｔｅｒｉｓｔｉｃｓ ｏｆ ｐｏｌｙｃｏｎｄｅｎｓａｔｉｏｎ ｏｆ ａｃｔｉｃａｔｅｄ ｄｉｅｓｔｅｒｓ ｗｉｔｈ ｄｉａｍｉｎｅｓ．Ｅｆｆｅｃｔ ｏｆ ｔｈｅ ｎａｔｕｒｅ ｏｆ ｌｅａｖｉｎｇ ｇｒｏｕｐｓ ｏｎ ｐｏｌｙａｍｉｄｅｓ ｖｉｓｃｏｓｔｉｙ，”ｐａｇｅ ５
Attorney, Agent or Firm:
Iwao Yamaguchi
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