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Title:
SELECTIVE HYDROGENATION CATALYST, MANUFACTURING METHOD OF SELECTIVE HYDROGENATION CATALYST, AND SELECTIVE HYDROGENATION METHOD
Document Type and Number:
Japanese Patent JP2019089039
Kind Code:
A
Abstract:
To provide a selective hydrogenation catalyst using no noble metal, capable of controlling alkene selectivity depending on reaction conditions, and providing excellent alkene selectivity, a manufacturing method of the selective hydrogenation catalyst, and a selective hydrogenation method.SOLUTION: A selective hydrogenation catalyst consists of a powder Heusler alloy of Co(MnFe)(GaGe) (0≤x≤1, 0≤y≤0.3). The selective hydrogenation catalyst can be manufactured by arc melting a raw material weighted to be a composition of the Heusler alloy, conducting a homogenization treatment at 700°C to 1100°C for 1 hr. to 80 hr. and pulverizing an alloy after the homogenization treatment. Alkyne can be selectively hydrogenated to alkene by contacting alkyne and hydrogen in the presence of the selective hydrogenation catalyst.SELECTED DRAWING: Figure 1

Inventors:
KOJIMA TAKAYUKI
KAMEOKA SATOSHI
CAI AN BANG
Application Number:
JP2017220616A
Publication Date:
June 13, 2019
Filing Date:
November 16, 2017
Export Citation:
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Assignee:
UNIV TOHOKU
International Classes:
B01J23/889; B01J23/825; B01J23/835; B01J37/08; B22F9/04; C07C5/09; C07C11/04; C07C11/06; C22C19/07
Domestic Patent References:
JP2009529560A2009-08-20
Foreign References:
WO2017029165A12017-02-23
Other References:
ACS OMEGA, vol. 2, JPN7021003062, 19 January 2017 (2017-01-19), pages 147 - 153, ISSN: 0004566477
Attorney, Agent or Firm:
Atsushi Suda
Shuji Kusunoki