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Title:
ROLLED COPPER OR COPPER ALLOY FOIL WITH ROUGHENED SURFACE AND METHOD OF ROUGHENING ROLLED COPPER OR COPPER ALLOY FOIL
Document Type and Number:
WIPO Patent Application WO/2007/145164
Kind Code:
A1
Abstract:
A rolled copper or copper alloy foil having a roughened surface comprising fine copper particles, characterized by being obtained by subjecting a rolled copper or copper alloy foil to roughening plating with a plating bath containing copper sulfate (1-50 g/L in terms of Cu amount), 1-150 g/L sulfuric acid, and one or more additives selected among sodium octyl sulfate, sodium decyl sulfate, and sodium dodecyl sulfate under the conditions of a temperature of 20-50°C and a current density of 10-100 A/dm2. The rolled copper or copper alloy foil roughened is reduced in craters, which are a conspicuous defect characteristic of rolled copper or copper alloy foils having a roughened surface. Also provided is a rolled copper or copper alloy foil which has a high strength, strength of adhesion to resin layers, acid resistance, and resistance to tin plating solutions. It further has a high peel strength and is satisfactory in suitability for etching and gloss. It is suitable for use in producing a flexible printed wiring board bearing a fine wiring pattern. Furthermore provided is a method of roughening the foil.

Inventors:
KOBAYASHI YOUSUKE (JP)
MIKI ATSUSHI (JP)
YAMANISHI KEISUKE (JP)
Application Number:
PCT/JP2007/061720
Publication Date:
December 21, 2007
Filing Date:
June 11, 2007
Export Citation:
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Assignee:
NIPPON MINING CO (JP)
KOBAYASHI YOUSUKE (JP)
MIKI ATSUSHI (JP)
YAMANISHI KEISUKE (JP)
International Classes:
C25D7/06; C22C9/00; C22C9/02; C22C9/04; C22C9/06; C25D3/38; C25D3/58; H05K1/09
Foreign References:
JP2005340635A2005-12-08
JP2005248323A2005-09-15
JP2000273684A2000-10-03
JPH0617258A1994-01-25
Other References:
TSURU Y. ET AL.: "Denkyoku ni Fuchaku shita Suiso Kiho ni yoru Furyoku o Riyo shita Nickel Mekki ni Okeru Shitsujunzai no Hyoka", THE JOURNAL OF THE SURFACE FINISHING SOCIETY OF JAPAN, vol. 56, no. 1, 2005, pages 41 - 45, XP003020638
Attorney, Agent or Firm:
OGOSHI, Isamu (Daini-Toranomon Denki Bldg. 5F,3-1-10 Toranomon, Minato-ku, Tokyo 01, JP)
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