| EP0345180A1 | 1989-12-06 | |||
| US4726709A | 1988-02-23 | |||
| EP0688904A1 | 1995-12-27 | |||
| DE2552516A1 | 1977-05-26 | |||
| US3351317A | 1967-11-07 |
| 1. | A glass consisting essentially of (in mole percent) :. |
| 2. | A glass according to claim 1, having an NVIS radiance not exceeding 1.7 x 10 with a lighting source of 0. |
| 3. | 1 fL luminance. |
| 4. | A glass according to claim 2, having an NVIS radiance not exceeding 1.7 x 10" with a lighting source of 0.1 fL luminance. |
| 5. | A glass according to claim 1, having a thickness of 3 mm. |
| 6. | A glass according to claim 1, having a thickness of 2 mm. |
| 7. | A glass according to claim 1, having a thickness of 1.5 mm. |
| 8. | A glass according to claim 1, having a thickness of 1 mm. |
| 9. | A method of rendering light sources compatible with NVIS goggles, comprising filtering said light sources with a glass of claim 1. |
| 10. | A method of rendering an image visible to an NVIS goggle, in the presence of IR radiation, comprising filtering said radiation with a glass of claim 1. |
| 11. | An optical filter consisting essentially of a glass of claim 1. |
| 12. | A filtered light source consisting essentially of an incandescent bulb and a filter of claim 11. |
| 13. | A glass consisting essentially of (in mole percent) : P2Os 4359 Si02 09 A1203 711 Li20 05 Na20 015 K20 015 MgO 015 CaO 00.5 BaO 07 ZnO 07 Ce02 00.5 CuO 721 V205 0.070.7 Nd203 01.5, wherein said glass also contains not more than 1.5 Pr60,|, has a photopic transmission of at least 10% at full rated voltage and a color space of NVIS Green B. |
| 14. | A method of rendering light sources compatible with NVIS goggles, comprising filtering said light sources with a glass of claim 13. |
| 15. | A method of rendering an image visible to an NVIS goggle, in the presence of IR radiation, comprising filtering said radiation with a glass of claim 13. |
| 16. | An optical filter consisting essentially of a glass of claim 13. |
| 17. | A filtered light source consisting essentially of an incandescent bulb and a filter of claim 13. |
| 18. | A glass consisting essentially of (in mole percent) : P205 4359 Siθ2 09 A1203 711 Li20 015 Νa20 015 K20 015 MgO 015 CaO 00.5 BaO 07 Zno 07 Ce02 00.5 CuO 721 V205 0.070.7 Pr60„ 01.5 Nd203 01.5 Nb205 03 B203 03 Y203 03 Cr203 01 having a photopic transmission of at least 10% at full rated voltage and a color space of NVIS Green A. |
| 19. | A glass according to claim 1, consisting essentially of: P205 4555 Si02 0.57 A1203 810 Li20 26 Na20 17 K20 313 MgO 012 CaO 00.3 BaO 05 ZnO 05 Ce02 0.20.4 CuO 920 V205 0.150.40 ■Pr6O 01.0 Nd203 01.0 Nb205 02 B203 02 Y203 02 Cr203 00.5 . |
| 20. | A glass consisting essentially of (in mole percent) : P205 4359 Si02 09 A1203 711 Li20 015 Na20 015 K20 015 MgO 015 CaO 00.5 BaO 07 ZnO 07 Ce02 00.5 CuO 721 V205 0.070.7 Nd203 01.5 Nb205 03 B203 03 Y203 03 Cr2o3 01, wherein said glass also contains not more than 1.5 Pr601lr has a photopic transmission of at least 8% at full rated voltage and a color space of NVIS Green B. |
Background of the Invention Night vision devices are image intensification apparatuses that amplify the night ambient illuminated view by a factor of approximately 10. As used in aircraft, these devices usually take the form of goggles worn by the pilot. Night vision devices usually include a photocathode which converts photons into electrons, a multiplier, and a phosphor screen to convert electrons back into photons. The pilot therefore accordingly views the scene outside the aircraft as a phosphor image displayed in the goggle eyepiece. Cockpit lighting, of instruments, gauges and warning signals, must be "compatible" with the goggles, i.e., must not emit significant amounts of radiant energy in the range detected by the goggle, so as to avoid flaring and "blooming", resulting in erasure of the image, which occurs when a light source is inadequately filtered to remove a sufficient level of interfering radiation. Significant amounts of cockpit radiation in the goggle range can also result in shutdown of the goggle where automatic gain control is used. Therefore, cockpit instrumentation must emit limited amounts of red and very near infra-red (IR) radiation. Blue, blue-green and green glass filters have been used to modify emissions from light sources for this purpose.
The military Joint Logistics Commanders Ad Hoc Group for Aviation Lighting has promulgated specification MIL-L-
85762A specifying night vision device-compatible lighting for aircraft interiors. In this standard, four colors have been defined for various cockpit lighting tasks. "NVIS
(Night Vision Imaging System) Green A" is for primary, secondary and advisory lighting. Utilizing the 1976 CIE
Convention Green A has coordinates of a circle of radius
0.037, with the center at u* = 0.088, v « = 0.543. "NVIS Green B" is for special lighting components needing saturated (i.e., more nearly monochromatic) lighting for contrast. Green B has a radius of 0.057 with the center at u 1 = 0.131, V = 0.623. "NVIS Yellow" is used for master caution and warning signals, and has a radius of 0.083 with the center at u* = 0.274, v « = 0.622. "NVIS red" for warning signals is defined as u* = 0.450, v* = 0.550 with a radius at 0.060. These color spaces are set forth in
Figure 7; it is noted that the 1976 CIE convention values of u 1 and v* may be converted to the 1931 CIE convention values as follows:
3V 6.75 u' x = and y =
4.5 u « -12 V+9 4.5 u'-12 v'+9
Lighting emission in these colors visible to the NVIS is specified by the standard not to exceed certain levels defined for "radiance". NVIS radiance (NR) is the integral of the curve generated by multiplying the spectral radiance of the light source by the relative spectral response of the NVIS: 930
NR = Gr-S-N-dλ
450 where G r is the relative NVIS response, N is the spectral radiance of the lighted component in W/cm Sr nm, S is the ratio of required luminescence level for NVIS radiance defined by luminescence measured by the spectroradiometer, and dλ is 5 nm. The military NR standard requires that
displays not exceed 1.7 x 10 when the lighting produces 0.1 fL display luminance. Warning and master caution
-ft signals may be brighter, at levels of between 5.0 x 10 and 1.5 x 10 " with source luminance levels of up to 15 fL. for Class A Type I goggles.
Significant variations in NVIS radiance and color coordinates are common in filtered incandescent lighted devices. The primary cause is the relationship of these parameters to the spectral energy distribution of the light source(s) . The energy distribution of an incandescent lamp is fundamentally related to filament operating temperature. Filament temperature varies strongly with operating voltage, and also varies somewhat from lamp to lamp due to minor differences in filaments. Filtered light sources which meet the above criteria must also be visible in daylight conditions. Consequently, filters must possess acceptable "photopic transmission" , a measure of visual readability of displays in which a light source is filtered for NVIS compatibility. The value of photopic transmission is calculated by an integration from 380 to 780 nm considering eye response, glass transmission, and radiance of the source, divided by eye response times unfiltered source radiance. The integration is usually performed at 5 to 10 nm increments. Typical procedures for the calculation of transmission values are set forth in the Handbook of Colorimetry, Technology Press, MIT, 1936 pp. 33-35.
Summary of the Invention The present invention provides glasses for use in the production of filters suitable for compatibility of light sources for use with night vision devices. The glasses have the following composition:
Oxide
P 2 0 5
Si0 2
A1 2 0 3
Li 2 0
Na 2 0
K 2 0
MgO
CaO
BaO
ZnO
Ce0 2
CuO
V 2 0 5
Nd 2 0 3
An additionally preferred embodiment is the use of Li 2 0 in an amount of 0-15 mole%, preferably 2-6 mole%, even more preferably the amount of Li0 2 is 0-5 or 5-15 mole%, or 2-4 or 4-6 mole%. Another additionally preferred embodiment is the use of K 2 0 in an amount of 3-13 mole%, even more preferably 3-5 or 5-13 mole%.
Also preferred are glasses further comprising the following oxides, in addition to those above:
General Mole % Preferred Mole"
Oxide Input Range Input Range
Nb 2 0 5 0-3 0-2 B 2 0 3 0-3 0-2 Y 2 0 3 0-3 0-2 Cr 2 0 3 0-1 0-0.5
Even more preferably, the four oxide components above are present in an amount of at least 0.1 mole%.
Additional preferred range endpoints for copper are 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19 and 20. Additional preferred endpoints for vanadium are ,10, .15, .20, .25, .30, .35, .40, .45, .50, .55, .60 and .65.
Surprisingly, the glasses of the invention possess excellent photopic transmission, on the order of 10% or greater at full rated voltage (i.e., at a color temperature of 2100-2150K) for Green A, and about 8-10% or greater for Green B, despite the inclusion of vanadium along with copper in the composition. Copper attenuates the near infrared red region by virtue of its broad band infrared absorption, as well as visually coloring the glass blue.
The addition of vanadium produces visible region absorp- tions which bias the chromaticity toward the green and aid in 600-650 nm region attenuation. In combination, one would expect the photopic transmission of the glass to decrease as these elements are combined. However, when vanadium is added in the proportions in accordance with the invention, surprisingly, the photopic transmission is increased.
After a maximum desirable value of vanadium ions, the photopic transmission begins to decrease.
As can be seen from page 84 of Colour Generation and
Control in Glass by Bamford, vanadium should be an oxidiz- ing agent for copper; therefor, the inclusion of vanadium, in the V state, will enhance the concentration of the Cu population at the expense of the v population. The reaction can be written as follows:
V +5 ^ V +3 + 2e " 2Cu +1 r* 2Cu +2 - 2e
As the population of V increases the visual transmis¬ sion should be impaired due to the position of the optical absorption bands of V * in the visible part of the electro¬ magnetic spectrum. Optical Absorption of Glasses, George H. Sigel, tr. What is surprising, when the correct amount of V 2 0 5 is added to the batch, is that an increase in phototopic (visual) transmittance is observed; as detailed in the Examples. The actual amount of V 2 0 5 required to optimize photopic transmission is dependent upon the total copper content and the base glass composition, and can be determined by
routine parametric transmission experimentation as per the Examples.
The glasses of the invention are prepared by conventional melting techniques and can be molded into any desired shape using conventional glass handling techniques, e.g., into faceplates, windows, lenses, etc. In addition, the glasses of the invention may be repressed into any desired shape or redrawn into tubing for, e.g., fabrication of jackets for incandescent bulbs. Filters made from the glasses of the invention are effective to produce NVIS Green A or Green B colored light from any source, and are preferably used but are not limited to filter incandescent sources.
Where Green B is desired, the glasses contain praseo- dymium and chromium in an amount effective to produce that color.
Filters produced from glasses of the invention preferably have thicknesses of 3, 2 , 1.5 or 1 mm. The transmission spectrum of the filters varies according to thickness, however the spectrum may be optimized according to routine parametric transmission experiments varying the filter thickness, such as those in the examples.
Description of the Drawings
The data presented in Figure 1 and Figure 4 shows variation in color coordinates and NVIS radiance over the operating range of several types of miniature lamps commonly used by manufacturers of illuminated avionics devices.
Figures 2 and 5 show transmittance of light as a function of wavelength.
Figures 3 and 6 show the photopic transmittance of filters as a function of color temperature.
Figure 7 defines the color space occupied by the glasses of the invention (NVIS Green A and B) .
Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The following preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever.
In the foregoing and in the following examples, all temperatures are set forth uncorrected in degrees Celsius and unless otherwise indicated, all parts and percentages are expressed in mole percent.
The entire disclosures of all applications, patents and publications, cited above and below, are hereby incorporated by reference.
TABLE 1
? D
o :
TABLE 2 TEST MELT DATA ON TWO- LITER NVGA-33 GLASS SAMPLE PRODUCTION
TEST MELT NUMBER
NVGA-33 NVGA-33 NVGA-33 NVGA-33 2L/1 2L/2 2L/3 2L/4
Fi lter Appl i cati on (3 mm) (3 mm) (3 mm) (3 mm) Green A (thickness)
Compositi on (mol e % Input)
PA 51.97 51.97 51.97 51.97 Si 0 2 0.92 - 0.92 0.92 0.92
A1 2 0 3 9.25 9.25 9.25 9.25
Li 2 0 2.77 2.77 2.77 2.77
Na 2 0 6.45 6.45 6.45 6.45
K 2 0 6.45 6.45 6.45 6.45
MgO 9.33 9.33 9.33 9.33
CaO 0.17 0.17 0.17 0.17
Ce0 2 0.32 0.32 0.32 0.32
CuO 12.21 12.21 12.21 12.21 0.184 0.184 0.184 0.184
Properties
Photopic Transmission for 15.0 15.1 14.7 15.6 2100K Incandescent niu inant Source
Meet Radiance Requirements YES YES YES YES for Near Infrared Attenuation as per MIL-L-84762A i.e.
NR = ≤ 1.7 x 10 "10
Meet Green A Chromaticity YES YES YES YES Requirements
10 TABLE 3 TEST MELT DATA ON TWO -LITER NVGA-29 GLASS SAMPLE PRODUCTION
TEST MELT NUMBER
NVGA-29 NVGA-29 NVGA-29 NVGA-29 2L/1 2L/2 2L/3 2L/4
Filter Application (2 mm) (2 mm) (2 mm) (2 mm) Green A (thickness)
Composition (mole % Input)
PA 48.97 48.97 48.97
Si0 2 3.92 3.92 3.92
A1 2 0 3 9.25 9.25 9.25
Li 2 0 2.77 2.77 2.77
Na 2 0 3.13 3.13 3.13
K 2 0 6.45 6.45 6.45
MgO 9.33 9.33 9.33
CaO
Ce0 2 0.32 0.32 0.32
CuO 15-53 15.53 15.53 0.352 0.352 0.352
Properties
Photopic Transmission for 13.5 13.7 13.9 13.8 2100K Incandescent πiuminant Source
Meet Radiance Requirements YES YES YES YES for Near Infrared Attenuation as per MIL-L-84762A i.e.
NR = ≤ 1.7 x 10 "10
Meet Green A Chromaticity YES YES YES YES Requirements
TABLE 4
TEST MELT DATA ON TWO- LITER NVGA GLASS
TEST MELT NUMBER
NVGA- 54 NVGA- 58 NVGA- 59 2L/1 2L/1 2L/1
Fi lter Appl ication (2 mm) (2 mm) (2 mm) Green A (thickness)
Composition (mole % Input)
P 2 0 5 48.97
Si0 2 3.92
A1 2 0 3 8.25
Li 2 0 2.77
Na 2 0 3.13
K 2 0 6.45
MgO 9.33
CaO
Ce0 2 0.32
CuO 15.53
V 2 0 5 0.352
Nb 2 0 5
Y 2 0 5 1.00 B 2 0 3 1.00
Properties
Photopic Transmission for 13.8 13.4 15.1 2100K Incandescent Il lu inant Source
Meet Radiance Requi rements YES YES YES for Near Infrared Attenuation as per MIL-L-84762A i .e.
NR = ≤ 1 . 7 x 10 "10
Meet Green A Chromaticity YES YES YES Requirements
Example A
A 2 mm filter is produced from a glass in accordance with the preceding examples, and determined to have the ollowing characteristics: Refractive Index, n d 1.547± 0.005
Density (g/cm 3 ) 2.77
Thermal Expansion Coefficient
-50-100°xl0 7 °C 1 76
20-200°Xl0 7 °C 1 89 Softening Pt.-10 7*6 (°C) 543
Annealing Pt.-10 13 (°C) 453 Passed thermal shock test as per MIL-STD-202F
Method 107F Condition B Passed Humidity test as per MIL-STD-202 Method 107 Condition A
Example B
A 3 mm filter is produced from a glass in accordance with the preceding examples, and determined to have the following characteristics: Refractive Index, n d 1.543± 0.005
Density (g/cm ) 2.75
Thermal Expansion Coefficient
-50-l00°xl0 7 °C 1 85
20-200°Xl0 7 °C 1 97 Softening Pt.-10 7'6 ("C) 511
Annealing Pt.-10 13 (°C) 444 Passed thermal shock test as per MIL-STD-202F
Method 107F Condition B Passed Humidity test as per MIL-STD-202 Method 107 Condition A
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