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Title:
ALKYL XANTHATE COMPOUND, PREPARATION THEREOF AND USE THEREOF
Document Type and Number:
Japanese Patent JPH03291265
Kind Code:
A
Abstract:

NEW MATERIAL:An alkyl xanthate compound of formula I (R1 is 1-18C alkyl).

EXAMPLE: Xylylene bis(ethyl xanthate).

USE: Useful as a photopolymerization initiator. The compound of formula I is employed for a polymerization reaction to prepare a polymer slightly having a color and capable of being controlled into various mol. wts.

PREPARATION: An aliphatic alcohol of formula II (R2 is 1-18C alkyl) is reacted with an alkali metal hydroxide or alkali metal, with carbon disulfide and subsequently with para xylylene dichloride to provide the compound of formula I. When a polymer is prepared, the prepared crude product of formula I is re-crystallized in benzene/methanol solvent for purification, mixed with a radically polymerizable monomer and irradiated with UV rays.


Inventors:
YAMAKAWA HIROSHI
OZOE SHINJI
Application Number:
JP9012290A
Publication Date:
December 20, 1991
Filing Date:
April 06, 1990
Export Citation:
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Assignee:
TOSOH CORP
International Classes:
G03F7/031; C07C329/16; C08F2/50; (IPC1-7): C07C329/16; C08F2/50; G03F7/031