Title:
含フッ素芳香族化合物及びその製造方法
Document Type and Number:
Japanese Patent JP7433968
Kind Code:
B2
Abstract:
To provide new fluorine-containing aromatic compounds with various substituents introduced therein, and production methods thereof.SOLUTION: A fluorine-containing aromatic compound is represented by the specified general formula (1). A production method of the fluorine-containing aromatic compound comprises reacting a fluorine-containing bisalkyne compound represented by the specified general formula (2) with an alkyne compound represented by the specified general formula (3) in the presence of a catalyst to obtain the fluorine-containing aromatic compound represented by the general formula (1).SELECTED DRAWING: None
Inventors:
Tomohiro Ago
Hiroki Fukumoto
Toshio Kubota
Shogo Saruwatari
Tomohiro Shirai
Shinichi Ishikawa
Hiroki Fukumoto
Toshio Kubota
Shogo Saruwatari
Tomohiro Shirai
Shinichi Ishikawa
Application Number:
JP2020024020A
Publication Date:
February 20, 2024
Filing Date:
February 17, 2020
Export Citation:
Assignee:
Tosoh Finechem Corporation
International Classes:
C07C23/36; C07C17/275; C07C29/32; C07C31/38; C07C41/30; C07C43/225; C07D213/26
Foreign References:
| WO2019021885A1 |
Other References:
Cao, Hai-Ping; Xiao, Ji-Chang; Chen, Qing-Yun,Fluoroalkylation of aromatics: An intramolecular radical cyclization of 4-chloro-1,1,2,2,3,3,4,4-octafluorobutylbenzenes,Journal of Fluorine Chemistry,2006年,Vol.127, No.8,pp.1079-1086,DOI:10.1016/j.jfluchem.2006.05.013
Kaplan, Peter T.; Xu, Long; Chen, Bo; McGarry, Katherine R.; Yu, Siqi; Wang, Huan; Vicic, David A.,Mild, Safe, and Versatile Reagents for (CF2)n Transfer and the Construction of Fluoroalkyl-Containing Rings,Organometallics,2013年,Vo.32, No.24,pp.7552-7558,DOI:10.1021/om401016k
Shozda, Raymond J.; Putnam, Robert E.,Diels-Alder reactions of 3,3,4,4-tetrafluorocyclobutene. Syntheses of some fluorinated benzocyclobutenes,Journal of Organic Chemistry,1962年,Vol.27,pp.1557-61
Tanaka, Ken; Sawada, Yayoi; Aida, Yusuke; Thammathevo, Maliny; Tanaka, Rie; Sagae, Hiromi; Otake, Yousuke,Rhodium-catalyzed convenient synthesis of functionalized tetrahydronaphthalenes,Tetrahedron,2010年,Vol.66, N.8,pp.1563-1569,DOI:10.1016/j.tet.2009.12.042
Tao, Ran; Umeyama, Tomokazu; Kurotobi, Kei; Imahori, Hiroshi,Effects of Alkyl Chain Length and Substituent Pattern of Fullerene Bis-Adducts on Film Structures and Photovoltaic Properties of Bulk Heterojunction Solar Cells,ACS Applied Materials & Interfaces,2014年,Vol.6, No.19,pp.17313-17322,DOI: 10.1021/am5058794
Doherty, Simon; Knight, Julian G.; Smyth, Catherine H.; Harrington, Ross W.; Clegg, William,Rhodium-Catalyzed Double [2 + 2 + 2] Cycloaddition of 1,4-Bis(diphenylphosphinoyl)buta-1,3-diyne with Tethered Diynes: A Modular, Highly Versatile Single-Pot Synthesis of NU-BIPHEP Biaryl Diphosphines,Organic Letters,2007年,Vol.9, No.23,pp.4925-4928,DOI:10.1021/ol702390p
Windler, G. Kenneth; Zhang, Mao-Xi; Zitterbart, Robert; Pagoria, PhilipF.;Vollhardt, K. Peter C.,En Route to Dinitroacetylene: Nitro(trimethylsilyl)acetylene and Nitroacetylene Harnessed by Dicobalt Hexacarbonyl,Chemistry - A European Journal,2012年,Vol.18, No.21,DOI: 10.1002/chem.201200473
Srinivasan, Ramji; Farona, Michael F.,Synthesis of benzocyclobutenes from reactions of α,ω-diynes catalyzed by niobium(V) and tantalum(V) halides,Journal of Molecular Catalysis,1989年,Vol.53, No.2,pp.203-8
Kaplan, Peter T.; Xu, Long; Chen, Bo; McGarry, Katherine R.; Yu, Siqi; Wang, Huan; Vicic, David A.,Mild, Safe, and Versatile Reagents for (CF2)n Transfer and the Construction of Fluoroalkyl-Containing Rings,Organometallics,2013年,Vo.32, No.24,pp.7552-7558,DOI:10.1021/om401016k
Shozda, Raymond J.; Putnam, Robert E.,Diels-Alder reactions of 3,3,4,4-tetrafluorocyclobutene. Syntheses of some fluorinated benzocyclobutenes,Journal of Organic Chemistry,1962年,Vol.27,pp.1557-61
Tanaka, Ken; Sawada, Yayoi; Aida, Yusuke; Thammathevo, Maliny; Tanaka, Rie; Sagae, Hiromi; Otake, Yousuke,Rhodium-catalyzed convenient synthesis of functionalized tetrahydronaphthalenes,Tetrahedron,2010年,Vol.66, N.8,pp.1563-1569,DOI:10.1016/j.tet.2009.12.042
Tao, Ran; Umeyama, Tomokazu; Kurotobi, Kei; Imahori, Hiroshi,Effects of Alkyl Chain Length and Substituent Pattern of Fullerene Bis-Adducts on Film Structures and Photovoltaic Properties of Bulk Heterojunction Solar Cells,ACS Applied Materials & Interfaces,2014年,Vol.6, No.19,pp.17313-17322,DOI: 10.1021/am5058794
Doherty, Simon; Knight, Julian G.; Smyth, Catherine H.; Harrington, Ross W.; Clegg, William,Rhodium-Catalyzed Double [2 + 2 + 2] Cycloaddition of 1,4-Bis(diphenylphosphinoyl)buta-1,3-diyne with Tethered Diynes: A Modular, Highly Versatile Single-Pot Synthesis of NU-BIPHEP Biaryl Diphosphines,Organic Letters,2007年,Vol.9, No.23,pp.4925-4928,DOI:10.1021/ol702390p
Windler, G. Kenneth; Zhang, Mao-Xi; Zitterbart, Robert; Pagoria, PhilipF.;Vollhardt, K. Peter C.,En Route to Dinitroacetylene: Nitro(trimethylsilyl)acetylene and Nitroacetylene Harnessed by Dicobalt Hexacarbonyl,Chemistry - A European Journal,2012年,Vol.18, No.21,DOI: 10.1002/chem.201200473
Srinivasan, Ramji; Farona, Michael F.,Synthesis of benzocyclobutenes from reactions of α,ω-diynes catalyzed by niobium(V) and tantalum(V) halides,Journal of Molecular Catalysis,1989年,Vol.53, No.2,pp.203-8
Attorney, Agent or Firm:
Norio Hagi