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Title:
FORMYLATION OF AROMATIC COMPOUND
Document Type and Number:
Japanese Patent JPH1017520
Kind Code:
A
Abstract:

To provide a method for formylating an aromatic compound by which a formylation of an aromatic compound is performed to provide an aromatic aldehydes useful as an intermediate for a dye, a medicine or an agrochemical in high yield and high purity by using bis(trichloromethyl) carbonate and formaldehydes without using harmful phosgene, sulfur or a phosphorus compound.

This method for formylating an aromatic compound comprises a formylation of (A) an aromatic compound {e.g. benzene, naphthalene, pyrrole and isothiazole, each of which may be substituted with a group of an alkyl, an alkoxy, a dialkylamino, an alkylarylamino, etc.} with (B) a complex of bis(trichloromethyl) carbonate (B1) and formamides (B2) such as N,N- dimethylformamide or N-methylformanilide. Moreover, the formylation is preferably performed at 20-150°C, especially 30-100°C.


Inventors:
HAYASHI SEIICHI
Application Number:
JP18429996A
Publication Date:
January 20, 1998
Filing Date:
June 26, 1996
Export Citation:
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Assignee:
NIPPON KAYAKU KK
International Classes:
C07C45/45; C07C47/52; C07C47/546; C07C221/00; C07C223/06; (IPC1-7): C07C47/52; C07C45/45; C07C47/546; C07C221/00; C07C223/06