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Title:
IMPROVED METHOD FOR PRODUCING LOWLY ODOROUS POLYPHENYLENE ETHER RESIN
Document Type and Number:
Japanese Patent JPH02215834
Kind Code:
A
Abstract:

PURPOSE: To obtain a lowly odorous polyphenylene ether resin by removing odorous impurities being by-products accumulated in the polymerization solvent in the production of a polyphenylene ether by distilling the solvent and recirculating the purified solvent into the polymerization system.

CONSTITUTION: In a continuous method for producing a polyphenylene ether resin, which comprises oxidatively coupling phenol in the presence of a catalyst in a solvent containing a normally liquid aromatic hydrocarbon in a polymerization zone till the formation of a polyphenylene ether resin and by-products are substantially completed, recovering the resin by adding a 1-6C alcohol to the polymer solution and recovering and recirculating the aromatic hydrocarbon containing the by-products, the aromatic hydrocarbon and the by-products are separated from each other by distillation to lower the content of the by-products, and the aromatic hydrocarbon substantially free from the by-products is recirculated into the polymerization zone.


Inventors:
JIYON PIITAA BEINBISHIYASU
Application Number:
JP33245289A
Publication Date:
August 28, 1990
Filing Date:
December 20, 1989
Export Citation:
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Assignee:
GEN ELECTRIC
International Classes:
C08G65/38; C08G65/44; C08G65/46; (IPC1-7): C08G65/44
Domestic Patent References:
JP45035070A
Foreign References:
US3383361A1968-05-14
Attorney, Agent or Firm:
Mitsuo Adachi (2 outside)