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Title:
OLIGOMER AND METHOD FOR PRODUCING THE SAME
Document Type and Number:
Japanese Patent JP2005076010
Kind Code:
A
Abstract:

To provide an oligomer capable of giving an excellent color tone and a low content of ether bonds as a by-product to polytrimethylene terephthalate obtained therefrom, and to provide a method for producing the oligomer, excellent in stability of continuous reaction processes.

An ester and/or the oligomer thereof are obtained from a lower alcohol ester of terephthalic acid and 1,3-propanediol, wherein the ester and/or the oligomer satisfy requisites (1) to (5) as follows: main repeating units thereof are composed of trimethylene terephthalate; (2) an average polymerization degree thereof is in the range of 1.5 to 7; (3) cyclic oligomers are contained in a range of 0 to 2.2 wt% based on the ester and/or the oligomer which are obtained from the lower alcohol ester of terephthalic acid and the 1,3-propanediol; (4) hydroxy groups are contained in a range of 92 to 100 mol wt% based on total end groups of the ester and/or the oligomer which are obtained from the lower alcohol ester of terephthalic acid and the 1,3-propanediol; and (5) bis(3-hydroxypropyl)ether is contained in the range of 0-0.3 wt%.


Inventors:
AZUMA YOICHIRO
FUJIMOTO KATSUHIRO
Application Number:
JP2003311666A
Publication Date:
March 24, 2005
Filing Date:
September 03, 2003
Export Citation:
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Assignee:
ASAHI KASEI CHEMICALS CORP
International Classes:
C08G63/78; (IPC1-7): C08G63/78
Domestic Patent References:
JP2003522263A2003-07-22
JPS4744726B1
JP2003119266A2003-04-23
Foreign References:
WO1999011709A11999-03-11