Title:
P-キラルホスホランおよびホスホ環式化合物並びにその不斉触媒反応における使用
Document Type and Number:
Japanese Patent JP4488739
Kind Code:
B2
Abstract:
Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrogenation, hydride transfer, allylic alkylation, hydrosilylation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation, Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and [m+n] cycloaddition. Processes for the preparation of the ligands are also described.
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Inventors:
Shoumu Chan
Wen Jun Tan
Wen Jun Tan
Application Number:
JP2003543975A
Publication Date:
June 23, 2010
Filing Date:
November 08, 2002
Export Citation:
Assignee:
The Penn State Research Foundation
International Classes:
C07F9/6568; B01J31/24; C07B31/00; C07B53/00; C07B61/00; C07C5/03; C07C5/333; C07C15/18; C07C41/20; C07C45/50; C07C45/69; C07C45/72; C07C51/36; C07C55/02; C07C67/283; C07C67/303; C07C69/157; C07C69/34; C07C69/612; C07C231/18; C07C233/05; C07C233/47; C07D217/04; C07D221/20; C07D307/42; C07D307/46; C07D333/24; C07F1/00; C07F7/00; C07F9/00; C07F9/6571; C07F9/6578; C07F9/6581; C07F9/6584; C07F11/00; C07F13/00; C07F15/00; C07F15/04; C07F17/02
Domestic Patent References:
| JP2002069086A |
Foreign References:
| WO2005117907A1 |
Other References:
HANAYA,T. et al,Synthesis of 5-deoxy-5-phenylphosphino- and 5-phenylphosphinyl-D- glucopyranoses,Bulletin of the Chemical Society of Japan,1991年,Vol.64, No.8,p.2398-401
RAJANBABU,T.V. et al,Synthesis, Characterization, and Applicability of Neutral Polyhydroxy Phospholane Derivatives and Their Rhodium(I) Complexes for Reactions in Organic and Aqueous Media,Journal of the American Chemical Society,2001年,Vol.123, No.42,p.10207-10213
DESCHAMPS,E. et al,A study of ferrocenylphospholes,Journal of Organometallic Chemistry,1987年,Vol.332, No.1-2,p.141-52
RAJANBABU,T.V. et al,Synthesis, Characterization, and Applicability of Neutral Polyhydroxy Phospholane Derivatives and Their Rhodium(I) Complexes for Reactions in Organic and Aqueous Media,Journal of the American Chemical Society,2001年,Vol.123, No.42,p.10207-10213
DESCHAMPS,E. et al,A study of ferrocenylphospholes,Journal of Organometallic Chemistry,1987年,Vol.332, No.1-2,p.141-52
Attorney, Agent or Firm:
Chika Takagi
Junji Yuda
Shoji Miwa
Junji Yuda
Shoji Miwa