Title:
重合体の製造方法
Document Type and Number:
Japanese Patent JP7226434
Kind Code:
B2
Abstract:
Provided is a method for manufacturing a polymer whereby a thiocarbonylthio group bound to an end of a polymer can be easily and highly selectively replaced by a hydrogen atom without using a metal. A polymer is produced by a method that comprises: step A for polymerizing a monomer in the presence of a thiocarbonylthio compound to give polymer T having a group [-SC(=S)R1] (wherein R1 represents a monovalent organic group) at one end; and step B for contacting polymer T with a thiol group-containing compound without adding a radical generator to thereby replace the group [-SC(=S)R1] in polymer T by a hydrogen atom.
Inventors:
Keio Nonoyama
Hidenori Naruse
Hidenori Naruse
Application Number:
JP2020510973A
Publication Date:
February 21, 2023
Filing Date:
March 26, 2019
Export Citation:
Assignee:
JSR CORPORATION
International Classes:
C08F8/00; C08F2/38
Domestic Patent References:
| JP2005307097A | ||||
| JP2015505881A | ||||
| JP2013136748A |
Other References:
CHONG Yen K. et al.,Thiocarbonylthio End Group Removal from RAFT-Synthesized Polymers by Radical-Induced Reduction,Macromolecules,2007年,Vol.40, No.13,p.4446-4455,ISSN 0024-9297
岡田幸雄、大野泰彦,チオカルボン酸によるメタクリル酸メチルの重合,高分子論文集,1986年,第43巻、第8号,459-463頁
岡田幸雄、大野泰彦,チオカルボン酸によるメタクリル酸メチルの重合,高分子論文集,1986年,第43巻、第8号,459-463頁
Attorney, Agent or Firm:
Yamada Tsuyoshi
Miho Hirota
Kyoko Hino
Miho Hirota
Kyoko Hino
Previous Patent: Control device, steering device, control method and program
Next Patent: Sheet-shaped article and method for producing the same
Next Patent: Sheet-shaped article and method for producing the same