Title:
PRODUCTION OF 4-PHENYL-1-BUTENE
Document Type and Number:
Japanese Patent JP3503150
Kind Code:
B2
Abstract:
PURPOSE: To obtain a 4-phenyl-1-butene in high purity and high yield, by reacting an allylmagnesium halide with a benzyl halide, useful as an intermediate material for the pesticides, the medicines or the electronic materials.
CONSTITUTION: By reacting an allylmagnesium halide with a benzyl halide of the formula I (where, R is H, halogen, 1-4C alkyl, 1-4C alkoxy; X is Cl, Br), if necessary, in the presence of a catalyst (e.g.; bis(1, 3- diphenylphosphinopropane) nickel chloride), at a temperature of 0 to 80°C to obtain a 4-phenyl-1-butene of the formula II. The allylmagnesium halide is obtained by reacting metallic magnesium with an allyl halide in a solvent (e.g.; toluene) at a temperature of-50 to 50°C. It is possible to obtain the compound of the formula II by using inexpensive and easily available raw materials.
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Inventors:
Hiroaki Fujishima
Yasunobu Miyamoto
Masayoshi Nanai
Yasunobu Miyamoto
Masayoshi Nanai
Application Number:
JP19603993A
Publication Date:
March 02, 2004
Filing Date:
August 06, 1993
Export Citation:
Assignee:
Sumitomo Chemical Co., Ltd.
International Classes:
B01J31/24; C07B61/00; C07C1/32; C07C15/44; C07C41/30; C07C43/215; (IPC1-7): C07C15/44; B01J31/24; C07C1/32; C07C41/30; C07C43/215
Domestic Patent References:
| JP543485A | ||||
| JP6072833A | ||||
| JP5111724A | ||||
| JP2160739A | ||||
| JP1106835A |
Other References:
Ｂｕｌｌ． Ｓｏｃ． Ｃｈｉｍ．，１９２８年，ｖｏｌ．４３，１３２２−８
Attorney, Agent or Firm:
Takashi Kuboyama
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