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Title:
PRODUCTION OF CYCLIC OLEFIN-BASED POLYMER
Document Type and Number:
Japanese Patent JP2001059004
Kind Code:
A
Abstract:

To efficiently obtain a cyclic olefin-based polymer of a homopolymer of a cyclic olefin without using a large amount of an organometallic compound by polymerizing specific cyclic olefins in the presence of a specific catalyst.

The objective polymer is obtained by polymerizing (C) cyclic olefins (preferably norbornene or the like) of the formula (R4 to R15 are each H, a 1-20C hydrocarbon or the like; k is ≥0) in the presence of a catalyst comprising (A) a zirconium compound [e.g. tetrakis (2,2,6,6-tetramethyl-3,5- heptanedionate)zirconium or the like] of the formula Zr(RlCOCR2COR3)nX4-n (R1 to R3 are each H or a 1-10C hydrocarbon with proviso that at least one of R1 to R3 is H and the case where all of R1 to R3 are H is omitted; X is a halogen or the like; n is 2 to 4) and (B) a boron compound [preferably triphenylmethyltetrakis(pentafluorophenyl)borate or the like] forming an ionic complex by reacting with a transition metal compound.


Inventors:
TAKASAKI KENJI
KISHIMOTO MANABU
Application Number:
JP23522099A
Publication Date:
March 06, 2001
Filing Date:
August 23, 1999
Export Citation:
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Assignee:
MITSUBISHI CHEM CORP
International Classes:
C08F132/08; C08F4/643; C08F4/659; C08F32/00; (IPC1-7): C08F132/08; C08F4/643
Attorney, Agent or Firm:
Hasegawa Moji