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Patent Searching and Data


Title:
PRODUCTION OF M-HYDROXYBENZALDEHYDE
Document Type and Number:
Japanese Patent JPS6393745
Kind Code:
A
Abstract:

PURPOSE: To obtain the titled compound in high yield, by using an alkali- containing alcohol, etc., as a solvent and a lanthanide element, etc., as a cocatalyst in oxidizing m-hydroxybenzyl alcohol with oxygen in the presence of platinum or palladium based catalyst.

CONSTITUTION: m-Hydroxybenzyl alcohol is oxidized with oxygen or an oxygen containing gas in the presence of a platinum and/or palladium based catalyst to produce m-hydroxybenzaldehyde useful as an intermediate for perfumes, medicines, etc. In the process, an alkali-containing 1W4C alcohol or mixed solvent of an alkali containing alcohol-water is preferably used as a solvent and a lanthanide element, e.g. cerium, samarium, europium, etc., or a compound thereof is present in the above-mentioned reaction system to suppress formation of m-hydroxybenzoic acid as a by-product. Thereby the aimed compound can be industrially and advantageously obtained from the above-mentioned raw material capable of producing the aimed compound at a relatively low cost in high yield.


Inventors:
OI TATSU
TAKENAKA SHINJI
Application Number:
JP23922686A
Publication Date:
April 25, 1988
Filing Date:
October 09, 1986
Export Citation:
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Assignee:
MITSUI TOATSU CHEMICALS
International Classes:
C07B61/00; B01J23/56; B01J23/63; C07C45/00; C07C45/38; C07C47/565; C07C67/00; (IPC1-7): B01J23/56; C07C45/38; C07C47/565