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Title:
PRODUCTION OF N-ALKYL-CARBAMATE
Document Type and Number:
Japanese Patent JPS6450850
Kind Code:
A
Abstract:

PURPOSE: To obtain a compd. which is useful as a plant disease control agent by bringing phenol or napthol and alkyl isocyanate into reaction in the presence of a specific catalyst with short time operation.

CONSTITUTION: The phenol or the napthol and the alkyl isocyanate are brought into reaction by using the bicycloamidine or bicycloguanidine contg. the ternary nitrogen bonded to the ketoiminic carbon of formula I of formula II (R1 and R2 are unsubstd., 1 to 5C alkyl or 3 to 5C alkenyl having a phenyl substituent; R5 is 1 to 5C alkyl or alkyl-aryl) as the catalyst. The objective is obtd. by effecting the reaction in a solvent, such as toluene at 0 to 50°C. The catalyst is exemplified by 1,5-diazabicyclo(4,3,0)nona-5-ene and is used at 0.0001 to 0.05 mol for each 1 mol of the phenol and napthol.


Inventors:
MIZIA FRANCO (IT)
RIVETTI FRANCO (IT)
ROMANO UGO (IT)
Application Number:
JP18707688A
Publication Date:
February 27, 1989
Filing Date:
July 28, 1988
Export Citation:
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Assignee:
ENICHEM SINTESI (IT)
International Classes:
B01J31/02; C07B61/00; C07C67/00; C07C271/26; C07C239/00; C07C271/06; C07C271/40; C07D307/83; C07D307/86; C07D317/20; C07D317/24; C07D317/46; C07D317/50; (IPC1-7): B01J31/02; C07B61/00; C07C125/06
Domestic Patent References:
JPS61183257A1986-08-15
JP46010188A
JPS63310861A1988-12-19
Attorney, Agent or Firm:
Katsuzo Asakura (1 outside)