REACTANT FOR PERFLUOROALKYLATION OF NUCLEOPHILIC SUBSTRATE WITH SIDIUM PERFLUOROALKANESULPHINATE IN OXIDIZING MEDIUM AND PROCESS THEREFOR

Japanese Patent JP2542129

B2

PURPOSE: To obtain a perfluoroalkylation reactant which is more easily used, gives a different ratio of the isomers in the products and is more economical as compared with a conventional technique.
CONSTITUTION: A perfluoroalkylation reactant is constituted of (a) a perfluoroalkanesulphinate ion and (b) a monoelectronic oxidizing system whose redox potential measured by using a saturated calomel electrode (ECS: Hg/ HgCl2) as a standard is greater than or equal to 1.20 V to perfluoroalkylate nucleophilic substrates with the reactant.

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JANNRUISU KUREBEERU
BERUNAADO RANGUROWA
ERIAN ROOREN
NAZARII ROIDO

JP11747191A

October 09, 1996

May 22, 1991

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RHONE POULENC CHIMIE

B01J23/46; B01J23/745; B01J27/057; B01J31/02; B01J31/20; C07B37/04; C07B45/06; C07B61/00; C07C37/11; C07C37/62; C07C39/24; C07C41/30; C07C43/225; C07C45/41; C07C45/54; C07C45/68; C07C49/167; C07C67/343; C07C209/74; C07C231/12; C07C319/14; C07C319/20; C07C323/03; C07C323/04; C07C323/52; C07D207/32; C07D231/44; C07D309/36; C07D309/38; (IPC1-7): C07B37/04; B01J23/46; B01J23/745; B01J27/057; B01J31/02; B01J31/20; C07C319/20; C07C323/03; C07C323/04; C07C323/52; C07D231/44; C07D309/36

【文献】CHEM.ABS.VOL.112、抄録番号157603C(1990)

Aoki Akira (4 outside)

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