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Title:
CATALYST FOR CARBONYLATION OF DIMETHYL ETHER TO PRODUCE METHYL ACETATE, PREPARATION METHOD THEREFOR, AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2021/092794
Kind Code:
A1
Abstract:
Disclosed are a catalyst for the carbonylation of dimethyl ether to produce methyl acetate, a preparation method therefor, and the use thereof. The catalyst contains a modified H-MOR molecular sieve, wherein the modified H-MOR molecular sieve is prepared by means of the exchange of an H-MOR molecular sieve with a pyridinium salt. Methyl acetate is produced by passing dimethyl ether and a raw material gas containing carbon monoxide through a reactor charged with an acidic molecular sieve catalyst which selectively regulates active sites, and performing a reaction under the conditions of a reaction temperature of 150-280°C, a reaction pressure of 0.5-25.0 MPa, and a space velocity of dimethyl ether of 0.2-4 h -1.

Inventors:
LIU SHIPING (CN)
LIU ZHONGMIN (CN)
ZHU WENLIANG (CN)
LIU HONGCHAO (CN)
LIU YONG (CN)
MA XIANGANG (CN)
Application Number:
PCT/CN2019/118018
Publication Date:
May 20, 2021
Filing Date:
November 13, 2019
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Assignee:
DALIAN INST CHEM & PHYSICS CAS (CN)
International Classes:
B01J29/18; C07C67/37; C07C69/14
Foreign References:
CN109985658A2019-07-09
CN109574839A2019-04-05
CN101613274A2009-12-30
CN108097325A2018-06-01
CN1989071A2007-06-27
US4205052A1980-05-27
Other References:
FLORIÁN JAN, KUBELKOVÁ LUDMILA, KOTRLA JOSEF: "Vibrational spectra of hydrogen-bonded complexes on zeolite surfaces as a benchmark for evaluating performance of ab initio methods. Complex with the pyridinium ion", JOURNAL OF MOLECULAR STRUCTURE, ELSEVIER AMSTERDAM, NL, vol. 349, 1 April 1995 (1995-04-01), NL, pages 435 - 438, XP055812214, ISSN: 0022-2860, DOI: 10.1016/0022-2860(95)08802-3
Attorney, Agent or Firm:
PERIODIC LAW FIRM (CN)
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