Title:
CATALYST FOR CARBONYLATION OF DIMETHYL ETHER TO PRODUCE METHYL ACETATE, PREPARATION METHOD THEREFOR, AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2021/092794
Kind Code:
A1
Abstract:
Disclosed are a catalyst for the carbonylation of dimethyl ether to produce methyl acetate, a preparation method therefor, and the use thereof. The catalyst contains a modified H-MOR molecular sieve, wherein the modified H-MOR molecular sieve is prepared by means of the exchange of an H-MOR molecular sieve with a pyridinium salt. Methyl acetate is produced by passing dimethyl ether and a raw material gas containing carbon monoxide through a reactor charged with an acidic molecular sieve catalyst which selectively regulates active sites, and performing a reaction under the conditions of a reaction temperature of 150-280°C, a reaction pressure of 0.5-25.0 MPa, and a space velocity of dimethyl ether of 0.2-4 h -1.
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Inventors:
LIU SHIPING (CN)
LIU ZHONGMIN (CN)
ZHU WENLIANG (CN)
LIU HONGCHAO (CN)
LIU YONG (CN)
MA XIANGANG (CN)
LIU ZHONGMIN (CN)
ZHU WENLIANG (CN)
LIU HONGCHAO (CN)
LIU YONG (CN)
MA XIANGANG (CN)
Application Number:
PCT/CN2019/118018
Publication Date:
May 20, 2021
Filing Date:
November 13, 2019
Export Citation:
Assignee:
DALIAN INST CHEM & PHYSICS CAS (CN)
International Classes:
B01J29/18; C07C67/37; C07C69/14
Foreign References:
CN109985658A | 2019-07-09 | |||
CN109574839A | 2019-04-05 | |||
CN101613274A | 2009-12-30 | |||
CN108097325A | 2018-06-01 | |||
CN1989071A | 2007-06-27 | |||
US4205052A | 1980-05-27 |
Other References:
FLORIÁN JAN, KUBELKOVÁ LUDMILA, KOTRLA JOSEF: "Vibrational spectra of hydrogen-bonded complexes on zeolite surfaces as a benchmark for evaluating performance of ab initio methods. Complex with the pyridinium ion", JOURNAL OF MOLECULAR STRUCTURE, ELSEVIER AMSTERDAM, NL, vol. 349, 1 April 1995 (1995-04-01), NL, pages 435 - 438, XP055812214, ISSN: 0022-2860, DOI: 10.1016/0022-2860(95)08802-3
Attorney, Agent or Firm:
PERIODIC LAW FIRM (CN)
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