Title:
CATALYST FOR CONTINUOUS PRODUCTION OF 1,1,1,3-TETRACHLOROPROPANE IN GAS-SOLID PHASE REACTION, PREPARATION METHOD THEREFOR AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2023/108788
Kind Code:
A1
Abstract:
A catalyst for the continuous production of 1,1,1,3-tetrachloropropane in a gas-solid phase reaction, a preparation method therefor and the use thereof. The catalyst comprises a zero-valent iron and phosphorus co-modified carbon material, which comprises a carbon material serving as a carrier, zero-valent iron loaded on the carrier and serving as an active component, and a phosphate functional group formed on the surface of the carbon material. The preparation method comprises: obtaining a catalyst for the continuous production of 1,1,1,3-tetrachloropropane in a gas-solid phase reaction by means of co-modification with a ferrous salt and an organophosphorus. Further provided is a method for continuously producing 1,1,1,3-tetrachloropropane in a gas-solid phase reaction. According to the catalyst, the active component zero-valent iron and the auxiliary component phosphate functional group are integrated on the carbon material carrier, such that the dependence of a traditional intermittent kettle type reaction on a liquid catalytic promoter is eliminated, and the continuous production of 1,1,1,3-tetrachloropropane on a gas-solid-phase fixed bed reactor is realized.
Inventors:
ZHANG YEXIN (CN)
ZHOU QIANG (CN)
ZHANG JIAN (CN)
ZHONG JUNLIANG (CN)
WANG XIUXIU (CN)
MU CHENGJUN (CN)
CHEN HUI (CN)
XIA LINBING (CN)
YANG JIE (CN)
WU GANG (CN)
YANG YONG (CN)
DU JILI (CN)
ZHOU QIANG (CN)
ZHANG JIAN (CN)
ZHONG JUNLIANG (CN)
WANG XIUXIU (CN)
MU CHENGJUN (CN)
CHEN HUI (CN)
XIA LINBING (CN)
YANG JIE (CN)
WU GANG (CN)
YANG YONG (CN)
DU JILI (CN)
Application Number:
PCT/CN2021/141027
Publication Date:
June 22, 2023
Filing Date:
December 24, 2021
Export Citation:
Assignee:
NINGBO INSTITUTE OF MATERIALS TECH & ENGINEERING CHINESE ACADEMY OF SCIENCES (CN)
NINGBO JUHUA CHEMICAL & SCIENCE CO LTD (CN)
NINGBO JUHUA CHEMICAL & SCIENCE CO LTD (CN)
International Classes:
B01J27/185; C07C17/275; C07C17/278; C07C19/01
Domestic Patent References:
| WO2020133554A1 | 2020-07-02 | |||
| WO2016128763A1 | 2016-08-18 | |||
| WO2018022500A1 | 2018-02-01 |
Foreign References:
| US20210009490A1 | 2021-01-14 | |||
| CN111056913A | 2020-04-24 | |||
| CN1986507A | 2007-06-27 | |||
| CN110813337A | 2020-02-21 |
Attorney, Agent or Firm:
NANJING LI & FENG INTELLECTUAL PROPERTY AGENCY(SPECIAL GENERAL PARTNERSHIP) (CN)
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