Title:
CATALYST FOR PRODUCING UNSATURATED CARBOXYLIC ACID, METHOD FOR PRODUCING UNSATURATED CARBOXYLIC ACID, AND METHOD FOR PRODUCING UNSATURATED CARBOXYLIC ESTER
Document Type and Number:
WIPO Patent Application WO/2018/181544
Kind Code:
A1
Abstract:
The present invention provides a catalyst for producing an unsaturated carboxylic acid, the catalyst being used to obtain an unsaturated carboxylic acid from an unsaturated aldehyde and containing a component A represented by formula (I) and a component B, which is a compound containing either an inorganic acid or an organic acid.
MxM'x'Oy (I)
(In formula (I), M is at least one type of element selected from the metal elements in period 4 of the periodic table, M' is at least one type of element selected from metal elements other than the metal elements in period 4 of the periodic table, and O is oxygen. x, x' and y indicate the atomic ratios of the components, in which x is an integer greater than or equal to 1, x' is 0 ≤ x' ≤ 0.4 for x = 1, and y is 0 or the atomic ratio of oxygen needed to satisfy the atomic ratios of the aforementioned components.)
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Inventors:
KANNO MITSURU (JP)
HIRATA JUN (JP)
NINOMIYA WATARU (JP)
KAMIYA YUICHI (JP)
OTOMO RYOICHI (JP)
HIRATA JUN (JP)
NINOMIYA WATARU (JP)
KAMIYA YUICHI (JP)
OTOMO RYOICHI (JP)
Application Number:
PCT/JP2018/012918
Publication Date:
October 04, 2018
Filing Date:
March 28, 2018
Export Citation:
Assignee:
MITSUBISHI CHEM CORP (JP)
UNIV HOKKAIDO NAT UNIV CORP (JP)
UNIV HOKKAIDO NAT UNIV CORP (JP)
International Classes:
B01J27/188; B01J27/053; C07C51/235; C07C57/055; C07B61/00
Domestic Patent References:
WO2016035573A1 | 2016-03-10 | |||
WO2009136537A1 | 2009-11-12 |
Foreign References:
CN104001542A | 2014-08-27 | |||
JP2015120133A | 2015-07-02 | |||
JP2005058909A | 2005-03-10 | |||
JPS586243A | 1983-01-13 | |||
JP2001137709A | 2001-05-22 |
Other References:
ZHOU,L. ET AL.: "Effect of vanadyl species in Keggin-type heteropoly catalysts in selective oxidation of methacrolein to methacrylic acid", JOURNAL OF CATALYSIS, vol. 329, 29 June 2015 (2015-06-29) - September 2015 (2015-09-01), pages 431 - 440, XP055612899
IWAKURA HIROKI ET AL.: "Selective oxidation of methacrolein using silica-supported chromium oxide catalyst with added tungstophosphoric acid", 120TH ANNUAL MEETING OF THE CATALYSIS SOCIETY OF JAPAN, no. 120, 5 September 2017 (2017-09-05), pages 270
IWAKURA HIROKI ET AL.: "Selective oxidation of methacrolein using silica-supported chromium oxide catalyst with added tungstophosphoric acid", 120TH ANNUAL MEETING OF THE CATALYSIS SOCIETY OF JAPAN, no. 120, 5 September 2017 (2017-09-05), pages 270
Attorney, Agent or Firm:
MIYAZAKI Teruo et al. (JP)
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