Title:
FULLERENE DERIVATIVE, PROCESS FOR PRODUCTION OF SAME, AND ALLERGEN ADSORBENT COMPRISING SAME
Document Type and Number:
WIPO Patent Application WO/2011/096349
Kind Code:
A1
Abstract:
Disclosed are: a novel fullerene derivative which can adsorb an allergen that causes hay fever within a short time and with high efficiency and does not re-release the allergen, and which does not contain a metal or the like that has any adverse influence on human bodies, and can be applied onto, can penetrate into or can be chemically bound to surfaces of various materials readily; and a process for producing the fullerene derivative. The fullerene derivative is characterized in that a halogen group and many hydroxy groups are bound directly to a fullerene core. When the halogen group is a chlorine, the derivative can be synthesized by the partial hydroxylation of a chlorinated fullerene or the partial chlorination of a hydroxylated fullerene.
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Inventors:
KOKUBO KEN (JP)
NOGUCHI TAKESHI (JP)
NOGUCHI TAKESHI (JP)
Application Number:
PCT/JP2011/051864
Publication Date:
August 11, 2011
Filing Date:
January 31, 2011
Export Citation:
Assignee:
UNIV OSAKA (JP)
TOTAI CO LTD (JP)
KOKUBO KEN (JP)
NOGUCHI TAKESHI (JP)
TOTAI CO LTD (JP)
KOKUBO KEN (JP)
NOGUCHI TAKESHI (JP)
International Classes:
C01B31/02; C07C25/22; C07C39/12; C07C39/40
Domestic Patent References:
| WO2008096763A1 | 2008-08-14 |
Foreign References:
| JP2008280290A | 2008-11-20 | |||
| JP2002193861A | 2002-07-10 | |||
| JP2005104907A | 2005-04-21 | |||
| JP2008094656A | 2008-04-24 | |||
| JP2007254246A | 2007-10-04 | |||
| JP2000005531A | 2000-01-11 | |||
| JP2002167332A | 2002-06-11 | |||
| JP2004204401A | 2004-07-22 | |||
| JP2002193861A | 2002-07-10 | |||
| JPH0748302A | 1995-02-21 |
Other References:
A.AVENT ET AL.: "In the first proven SN2' fullerene reaction, both C3 and C1 C6oF36 hydrolyse to C1 isomers of C6oF35OH that eliminate HF to give epoxides C6oF340; C6oF360 oxides are shown to be ethers, and a fourth isomer of C6oF36 exists", ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 1, no. 6, 21 March 2003 (2003-03-21), pages 1026 - 1033, XP008165183
A.ABDUL-SADA ET AL.: "Isolation and characterisation of fluorinated derivatives of [76]- and [78]fullerenes", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 2, vol. 12, no. 12, 1999, pages 2659 - 2666, XP008165185
See also references of EP 2535313A4
J. AM. CHEM. SOC., vol. 113, 1991, pages 9900
J. CHEM. SOC., CHEM. COMMUN., 1993, pages 1230
EUR. J. ORG. CHEM., 2005, pages 4951
ANGEW. CHEM. INT. ED., vol. 40, 2001, pages 2285
SCIENCE, vol. 256, 1992, pages 822
J. ORG. CHEM., vol. 59, 1994, pages 3960
SYNTH. COMMUN., vol. 35, 2005, pages 1803
ACS NANO, vol. 2, 2008, pages 37
FULLERENES, NANOTUBES, AND CARBON NANOSTRUCTURES, vol. 13, 2005, pages 331
A.ABDUL-SADA ET AL.: "Isolation and characterisation of fluorinated derivatives of [76]- and [78]fullerenes", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 2, vol. 12, no. 12, 1999, pages 2659 - 2666, XP008165185
See also references of EP 2535313A4
J. AM. CHEM. SOC., vol. 113, 1991, pages 9900
J. CHEM. SOC., CHEM. COMMUN., 1993, pages 1230
EUR. J. ORG. CHEM., 2005, pages 4951
ANGEW. CHEM. INT. ED., vol. 40, 2001, pages 2285
SCIENCE, vol. 256, 1992, pages 822
J. ORG. CHEM., vol. 59, 1994, pages 3960
SYNTH. COMMUN., vol. 35, 2005, pages 1803
ACS NANO, vol. 2, 2008, pages 37
FULLERENES, NANOTUBES, AND CARBON NANOSTRUCTURES, vol. 13, 2005, pages 331
Attorney, Agent or Firm:
MINAKA Eiji et al. (JP)
Inside of three Eiji (JP)
Inside of three Eiji (JP)
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