Title:
METAL COMPLEX HAVING AROMATIC LIGAND THAT CONTAINS NITROGEN ATOM
Document Type and Number:
WIPO Patent Application WO/2010/123131
Kind Code:
A1
Abstract:
Disclosed is a metal complex which contains a nitrogen-containing aromatic ligand having a dendritic molecular chain, and a copper (I) ion or a silver (I) ion. For example, a metal complex represented by composition formula (8) has excellent heat resistance. (In the formula, M+ represents a copper (I) ion or a silver (I) ion; L represents a ligand; X represents a counter ion; p represents a positive number; q and r each independently represents a number not less than 0; and R represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a carboxyl group, an amino group, an acylamino group, a silyl group, a hydroxyl group, an acyl group, a hydrocarbyl group, a hydrocarbyloxy group, a hydrocarbylthio group or a heterocyclic group, and the amino group, silyl group, hydrocarbyl group, hydrocarbyloxy group and hydrocarbylthio group may have a substituent.)
Inventors:
KURAMOCHI YUSUKE (JP)
KOBAYASHI NORIFUMI (JP)
HIGASHIMURA HIDEYUKI (JP)
KOBAYASHI NORIFUMI (JP)
HIGASHIMURA HIDEYUKI (JP)
Application Number:
PCT/JP2010/057308
Publication Date:
October 28, 2010
Filing Date:
April 19, 2010
Export Citation:
Assignee:
SUMITOMO CHEMICAL CO (JP)
KURAMOCHI YUSUKE (JP)
KOBAYASHI NORIFUMI (JP)
HIGASHIMURA HIDEYUKI (JP)
KURAMOCHI YUSUKE (JP)
KOBAYASHI NORIFUMI (JP)
HIGASHIMURA HIDEYUKI (JP)
International Classes:
C07D213/16; C07D471/04; C09K11/06; H01L51/50; C07F1/08; C07F1/10
Foreign References:
| JP2008063399A | 2008-03-21 | |||
| US20090143596A1 | 2009-06-04 | |||
| JPS6370257A | 1988-03-30 | |||
| JPS63175860A | 1988-07-20 | |||
| JPH02135359A | 1990-05-24 | |||
| JPH02135361A | 1990-05-24 | |||
| JPH02209988A | 1990-08-21 | |||
| JPH0337992A | 1991-02-19 | |||
| JPH03152184A | 1991-06-28 |
Other References:
SHU, M.: "Reversible Anion Exchanges of Porous Metal-Organic Frameworks: Syntheses and Structures of Silver Complexes with Novel Rigid Tripodal Nitrogen Ligands", CRYSTAL GROWTH AND DESIGN, vol. 6, no. 8, 2006, pages 1890 - 1896, XP008164527
SEWARD, C.: "Luminescent 2D macrocyclic networks based on starburst molecules: [{Ag(CF3S03)}1.5 (tdapb)] and [{Ag(N03)}3(tdapb)]", ANGEWANDTE CHEMIE, vol. 43, no. 22, 2004, ENGLISH, pages 2933 - 2936, XP055013136
ZHANG, X.: "Formation of two (6,3) networks showing structural diversity, Borromean topology and conformational chirality in the same crystal", CHEMICAL COMMUNICATIONS, vol. 41, 2007, pages 4242 - 4244, XP008164526
ZHANG, X.: "Discrete Chiral Single-Crystal Microtubes Assembled with Honeycomb Coordination Networks Showing Structural Diversity and Borromean Topology in One Single Crystal", CHEMISTRY OF MATERIALS, vol. 19, no. 19, 2007, pages 4630 - 4632, XP008164537
BRODBECK, R.: "Molecular Dynamics Simulations of Dendrimer-Encapsulated a-Keggin Ions in Trichloromethane Solution", JOURNAL OF PHYSICAL CHEMISTRY B, vol. 112, no. 16, 2008, pages 5153 - 5162, XP008163813
KIMURA, M.: "Energy transfer within ruthenium- cored rigid metallodendrimers", TETRAHEDRON LETTERS, vol. 41, no. 35, 2000, pages 6809 - 6813, XP004213954
K. R. KYLE ET AL., JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 113, 1991, pages 2954 - 2965
CHINESE JOURNAL OF CHEMISTRY, vol. 24, 2006, pages 1631 - 1638
CHINESE JOURNAL OF CHEMISTRY, vol. 24, 2006, pages 1631 - 1638
TETRAHEDRON LETTERS, vol. 41, 2000, pages 6809 - 6813
SEWARD, C.: "Luminescent 2D macrocyclic networks based on starburst molecules: [{Ag(CF3S03)}1.5 (tdapb)] and [{Ag(N03)}3(tdapb)]", ANGEWANDTE CHEMIE, vol. 43, no. 22, 2004, ENGLISH, pages 2933 - 2936, XP055013136
ZHANG, X.: "Formation of two (6,3) networks showing structural diversity, Borromean topology and conformational chirality in the same crystal", CHEMICAL COMMUNICATIONS, vol. 41, 2007, pages 4242 - 4244, XP008164526
ZHANG, X.: "Discrete Chiral Single-Crystal Microtubes Assembled with Honeycomb Coordination Networks Showing Structural Diversity and Borromean Topology in One Single Crystal", CHEMISTRY OF MATERIALS, vol. 19, no. 19, 2007, pages 4630 - 4632, XP008164537
BRODBECK, R.: "Molecular Dynamics Simulations of Dendrimer-Encapsulated a-Keggin Ions in Trichloromethane Solution", JOURNAL OF PHYSICAL CHEMISTRY B, vol. 112, no. 16, 2008, pages 5153 - 5162, XP008163813
KIMURA, M.: "Energy transfer within ruthenium- cored rigid metallodendrimers", TETRAHEDRON LETTERS, vol. 41, no. 35, 2000, pages 6809 - 6813, XP004213954
K. R. KYLE ET AL., JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 113, 1991, pages 2954 - 2965
CHINESE JOURNAL OF CHEMISTRY, vol. 24, 2006, pages 1631 - 1638
CHINESE JOURNAL OF CHEMISTRY, vol. 24, 2006, pages 1631 - 1638
TETRAHEDRON LETTERS, vol. 41, 2000, pages 6809 - 6813
Attorney, Agent or Firm:
NAKAYAMA, Tohru et al. (JP)
Toru Nakayama (JP)
Toru Nakayama (JP)
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