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Title:
METHOD FOR PREPARING HIGH-PERFORMANCE LITHIUM-CONTAINING ORGANIC SULFUR ELECTRODE MATERIAL AND INTEGRATED FLEXIBLE ELECTRODE
Document Type and Number:
WIPO Patent Application WO/2021/082347
Kind Code:
A1
Abstract:
Provided is a method for preparing a high-performance lithium-containing organic sulfur electrode material and an integrated flexible electrode. The present invention uses a method of using 1,3-diisopropenylbenzene having a diolefin bond and Li2S6 as precursors and using in-situ polymerization so as to carry out reaction and produce a lithium-containing organic sulfide Poly(Li2S6-r-DIB). As the synthesized lithium-containing organic sulfide Poly(Li2S6-r-DIB) shows good viscosity when heated to a certain temperature, same may be directly attached to a flexible conductive carbon cloth to thereby produce an integrated flexible electrode. The obtained flexible electrode has the advantages of having high capacity, high flexibility, a stable structure and so on.

Inventors:
ZHENG SHIYOU (CN)
YANG JUNHE (CN)
DONG FEI (CN)
PANG YUEPENG (CN)
Application Number:
PCT/CN2020/082850
Publication Date:
May 06, 2021
Filing Date:
April 01, 2020
Export Citation:
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Assignee:
UNIV OF SHANGHAI FOR SCIENCE AND TECHNOLOGY (CN)
International Classes:
H01M4/137; C08G75/0254
Domestic Patent References:
WO2013023216A12013-02-14
Foreign References:
CN110760063A2020-02-07
CN110148696A2019-08-20
CN110304657A2019-10-08
CN106450423A2017-02-22
Other References:
HOEFLING ALEXANDER, NGUYEN DAN THIEN, PARTOVI-AZAR POUYA, SEBASTIANI DANIEL, THEATO PATRICK, SONG SEUNG-WAN, LEE YOUNG JOO: "Mechanism for the Stable Performance of Sulfur-Copolymer Cathode in Lithium−Sulfur Battery Studied by Solid-State NMR Spectroscopy", CHEMISTRY OF MATERIALS, vol. 30, no. 9, 8 May 2018 (2018-05-08), pages 29153 - 2923, XP055807700, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.7b05105
ZHANG JUN, HUANG HUI, XIA YANG, LIANG CHU, GAN YONGPING, TAO XINYONG, ZHANG WENKUI: "Enhanced Electrochemical Performance of Lithium–Sulfur Batteries with Surface Copolymerization of Cathode", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 166, no. 3, 18 January 2019 (2019-01-18), pages A5349 - A5353, XP055807949, ISSN: 0013-4651, DOI: 10.1149/2.0531903jes
Attorney, Agent or Firm:
SHANGHAI BANGDE PATENT AGENCY (CN)
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