Title:
METHOD OF PRODUCING FULLERENE DERIVATIVE
Document Type and Number:
WIPO Patent Application WO/2007/010990
Kind Code:
A1
Abstract:
It is intended to provide a method whereby fullerene 1,3-dioxolane is conveniently produced at a high yield. Namely, fullerene 1,3-dioxolane is produced by reacting fullerene oxide with a carbonyl compound in the presence of a solid acid catalyst.
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Inventors:
TAJIMA YUSUKE (JP)
TANAKA KATUTOMO (JP)
TANAKA KATUTOMO (JP)
Application Number:
PCT/JP2006/314400
Publication Date:
January 25, 2007
Filing Date:
July 20, 2006
Export Citation:
Assignee:
RIKEN (JP)
TAJIMA YUSUKE (JP)
TANAKA KATUTOMO (JP)
TAJIMA YUSUKE (JP)
TANAKA KATUTOMO (JP)
International Classes:
C07D317/70; C07B61/00
Domestic Patent References:
| WO2005116006A1 | 2005-12-08 |
Foreign References:
| JP2005126357A | 2005-05-19 | |||
| JPS5993022A | 1984-05-29 | |||
| JP2003277373A | 2003-10-02 | |||
| JP2003196881A | 2003-07-11 |
Other References:
SHIGEMITSU Y. ET AL.: "Efficient acetalization of epoxy rings on a fullerene cage", CHEMISTRY LETTERS, vol. 33, no. 12, 2004, pages 1604 - 1605, XP003007706
TAJIMA Y. ET AL.: "Highly efficient acetalization of epoxide groups on fullerene", FULLERENE-NANOTUBES GENERAL SYMPOSIUM KOEN YOSHISHU, vol. 27TH, 28 July 2004 (2004-07-28), pages 161, XP003007707
SEO S. ET AL.: "Acetalization of fullerene epoxides with various carbonyl compounds", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, (2 F7-43), vol. 85TH, no. 2, 11 March 2005 (2005-03-11), pages 1342, XP003007708
YOSHIDA M. ET AL.: "Reaction of C60 with diacyl peroxides containing perfluoroalkyl groups. The first example of electron transfer reaction via C60+ in solution", TETRAHEDRON LETTERS, vol. 34, no. 47, 1993, pages 7629 - 7632, XP002994520
ELEMES Y. ET AL.: "Reaction of C60 with dimethyldioxirane-Formation of an epoxide and a 1,3-dioxolane derivative", ANGEW. CHEM. INT. ED. ENGL., vol. 31, no. 3, 1992, pages 351 - 353, XP003007709
WANG G.-W. ET AL.: "Reaction of sodium alkoxides with [60]fullerene: Formation of a 1,3-dioxolane derivative and involvement of O2 in a nucleophilic addition reaction of C60", JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, vol. 10, 1995, pages 1071 - 1072, XP002994519
TAJIMA Y. ET AL.: "Highly efficient acetalization of epoxide groups on fullerene", FULLERENE-NANOTUBES GENERAL SYMPOSIUM KOEN YOSHISHU, vol. 27TH, 28 July 2004 (2004-07-28), pages 161, XP003007707
SEO S. ET AL.: "Acetalization of fullerene epoxides with various carbonyl compounds", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, (2 F7-43), vol. 85TH, no. 2, 11 March 2005 (2005-03-11), pages 1342, XP003007708
YOSHIDA M. ET AL.: "Reaction of C60 with diacyl peroxides containing perfluoroalkyl groups. The first example of electron transfer reaction via C60+ in solution", TETRAHEDRON LETTERS, vol. 34, no. 47, 1993, pages 7629 - 7632, XP002994520
ELEMES Y. ET AL.: "Reaction of C60 with dimethyldioxirane-Formation of an epoxide and a 1,3-dioxolane derivative", ANGEW. CHEM. INT. ED. ENGL., vol. 31, no. 3, 1992, pages 351 - 353, XP003007709
WANG G.-W. ET AL.: "Reaction of sodium alkoxides with [60]fullerene: Formation of a 1,3-dioxolane derivative and involvement of O2 in a nucleophilic addition reaction of C60", JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, vol. 10, 1995, pages 1071 - 1072, XP002994519
Attorney, Agent or Firm:
SIKs & Co. (Kyobashi-Nisshoku Bldg. 8-7 Kyobashi 1-chom, Chuo-ku Tokyo31, JP)
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