Title:
NOVEL ALIPHATIC CHAIN-CONTAINING POLY(ALKYL-ARYL PIPERIDINIUM) POLYMER IONOMER, ANION EXCHANGE MEMBRANE, COMPOSITE MEMBRANE, AND MANUFACTURING METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2022/225357
Kind Code:
A1
Abstract:
The present invention relates to the synthesis of a poly(alkyl-aryl piperidinium) polymer, which has no aryl-ether bond in the polymer backbone, contains an aliphatic chain in a repeating unit, and has a piperidinium group introduced thereinto, and to the preparation of an anion exchange membrane therefrom and a composite membrane using same. The anion exchange membrane and the composite membrane using same according to the present invention have excellent alkaline stability and mechanical properties and very high ion conductivity. Furthermore, the membranes of the present invention reduce a phenyl adsorption effect of an electrode catalyst and exhibit high water permeation and power density and superior durability, and thus can be applied to membranes and binders for alkaline fuel cells or water electrolysis.
Inventors:
LEE YOUNG MOO (KR)
PARK JONG HYEONG (KR)
HU CHUAN (KR)
CHEN NANJUN (KR)
PARK JONG HYEONG (KR)
HU CHUAN (KR)
CHEN NANJUN (KR)
Application Number:
PCT/KR2022/005755
Publication Date:
October 27, 2022
Filing Date:
April 22, 2022
Export Citation:
Assignee:
IUCF HYU (KR)
International Classes:
C08G61/02; C08G61/12; C08J5/22; C25B13/08; H01M4/86; H01M8/083; H01M8/103; H01M8/1058; H01M8/1081
Foreign References:
| KR20100076902A | 2010-07-06 | |||
| CN104829814A | 2015-08-12 |
Other References:
CHEN NANJUN, HU CHUAN, WANG HO HYUN, KIM SUN PYO, KIM HAE MIN, LEE WON HEE, BAE JOON YONG, PARK JONG HYEONG, LEE YOUNG MOO: "Poly(Alkyl‐Terphenyl Piperidinium) Ionomers and Membranes with an Outstanding Alkaline‐Membrane Fuel‐Cell Performance of 2.58 W cm −2", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 60, no. 14, 29 March 2021 (2021-03-29), pages 7710 - 7718, XP055977808, ISSN: 1433-7851, DOI: 10.1002/anie.202013395
LONG CHUAN; WANG ZHIHUA; ZHU HONG: "High chemical stability anion exchange membrane based on poly(aryl piperidinium): Effect of monomer configuration on membrane properties", INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, vol. 46, no. 35, 26 March 2021 (2021-03-26), AMSTERDAM, NL, pages 18524 - 18533, XP086567832, ISSN: 0360-3199, DOI: 10.1016/j.ijhydene.2021.02.209
ANG ELISA Y.M.; TOH WILLIAM; YEO JINGJIE; LIN RONGMING; LIU ZISHUN; GEETHALAKSHMI K.R.; NG TENG YONG: "A review on low dimensional carbon desalination and gas separation membrane designs", JOURNAL OF MEMBRANE SCIENCE, vol. 598, 28 December 2019 (2019-12-28), NL , pages 1 - 29, XP086030486, ISSN: 0376-7388, DOI: 10.1016/j.memsci.2019.117785
HU CHUAN, PARK JONG HYEONG, KIM HAE MIN, WANG HO HYUN, BAE JOON YONG, KANG NA YOON, CHEN NANJUN, LEE YOUNG MOO: "Elucidating the role of alkyl chain in poly(aryl piperidinium) copolymers for anion exchange membrane fuel cells", JOURNAL OF MEMBRANE SCIENCE, vol. 647, 5 April 2022 (2022-04-05), NL , pages 1 - 11, XP055977810, ISSN: 0376-7388, DOI: 10.1016/j.memsci.2022.120341
LONG CHUAN; WANG ZHIHUA; ZHU HONG: "High chemical stability anion exchange membrane based on poly(aryl piperidinium): Effect of monomer configuration on membrane properties", INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, vol. 46, no. 35, 26 March 2021 (2021-03-26), AMSTERDAM, NL, pages 18524 - 18533, XP086567832, ISSN: 0360-3199, DOI: 10.1016/j.ijhydene.2021.02.209
ANG ELISA Y.M.; TOH WILLIAM; YEO JINGJIE; LIN RONGMING; LIU ZISHUN; GEETHALAKSHMI K.R.; NG TENG YONG: "A review on low dimensional carbon desalination and gas separation membrane designs", JOURNAL OF MEMBRANE SCIENCE, vol. 598, 28 December 2019 (2019-12-28), NL , pages 1 - 29, XP086030486, ISSN: 0376-7388, DOI: 10.1016/j.memsci.2019.117785
HU CHUAN, PARK JONG HYEONG, KIM HAE MIN, WANG HO HYUN, BAE JOON YONG, KANG NA YOON, CHEN NANJUN, LEE YOUNG MOO: "Elucidating the role of alkyl chain in poly(aryl piperidinium) copolymers for anion exchange membrane fuel cells", JOURNAL OF MEMBRANE SCIENCE, vol. 647, 5 April 2022 (2022-04-05), NL , pages 1 - 11, XP055977810, ISSN: 0376-7388, DOI: 10.1016/j.memsci.2022.120341
Attorney, Agent or Firm:
CHUNG HYUN PATENT & LAW FIRM (KR)
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