FARRUGGIA GIUSEPPE (US)
CUSHMAN THOMAS RICHARD (US)
TYAN YUAN-SHENG (US)
FARRUGGIA GIUSEPPE (US)
CUSHMAN THOMAS RICHARD (US)
WO2004013073A1 | 2004-02-12 |
EP1003229A1 | 2000-05-24 | |||
JPH0963771A | 1997-03-07 | |||
EP1388894A2 | 2004-02-11 |
Ia = 1000 x -^- = 1000 x — Eαuation 2 t pt a The short reduction layer 260 reduces the negative impacts of shorting defect 250 and raises the device performance to an acceptable level. The negative impact of shorting defects can be measured by a parameter f, ratio of the leakage current that flows through the shorting defects to the total device current:
f = Eαuation 2
To achieve an acceptable ratio f0 , the short reduction layer 260 needs to have a minimum through-thickness resistivity pt of y "- βloA Eαation 3
The selection of materials that can be used as an effective short reduction layer 260 depends therefore on the area A; the operatinug condition of OLED device 200, V0 and I0; the level of performance loss that can be tolerated, f0; the total area of shorting defects, α; and the thickness of short reduction layer 260, t, that can be incorporated into the device. The thickness of short reduction layer 260 is selected based on two considerations: 1). Typical OLED devices have total organic layer thickness of about 100 - 300 nm and the layer thickness is optically tuned to optimize the emission efficiency of the device. A short reduction layer becomes a part of the optical structure of the device and hence its thickness should not be over about 200 nm. Too thick a short reduction layer also increases manufacturing cost of the OLED device. 2) The short reduction layer needs to be thick enough to effectively cover the shorting defects. A reasonable lower limit is about 20 nm. The present invention prefers a short reduction layer in the thickness range of 20 nm to 200 nm. OLED devices are being used for many different applications. These OLED devices can have vastly different device area and operating conditions. For example, for lighting applications the OLED device tends to be divided into large light emitting segments (U.S. Patent No. 6,693,296), greater than one centimeter squared, that operate at relatively few levels of current densities. For area color displays, the pixels are smaller, maybe on the order of square millimeters, and the operating conditions again do not varied a lot. For high resolution pixilated OLED displays, either on active matrix or passive matrix back planes, the pixels are much smaller, on the order of 0.3 mm x 0.3 mm or smaller, and, in addition, the OLED devices need to provide a dynamic range. For an eight bit resolution the device operating current needs to have a range of IX to 256X. Equation 3 suggests that these different OLED devices will require vastly different materials as the short reduction layer. Example 1: As an illustration of the short reduction layer selection, the impact of shorting defects on a single pixel in a high resolution pixilated OLED display is analyzed. The analysis assumes the existence of one shorting defect of a certain size in a pixel. The results of the analysis will be the same if instead there are several smaller shorting defects, such as those caused by roughness of the substrate or the first electrode layer, with the same total area as the single defect. The size of the pixels is assumed to be 0.1 mm x 0.1 mm and the size of the defect is 1 μm x 1 μm, typical of the size of dust particles. A state of the art bottom emitting active matrix OLED display has about 200 cd/m2 luminance at full brightness. This brightness is achieved from an OLED display having an aperture ratio of about 0.25 and through a polarizer film of about 50% transmittance. The actual brightness at the OLED device surface at full brightness is therefore about 1600 cd/m2. With an eight-bit color depth, the OLED device needs also to operate down to about 6.3 cd/m2. The efficiency of a state-of-the-art OLED device is about 10 cd/A and the operating voltage is about 10 volts. This means the device has to operate from about 0.063 mA/cm2 to about 16 mA/cm . For this and the following examples, the device operating voltage is assumed to be independent of the operating current. In most real devices the operating voltage varies with the logarithm of the operating current. Over the about the two and half decade operating current range considered in these examples, the constant voltage assumption is therefore a reasonable and conservative assumption. The resistivity of a 20 run thick short reduction layer film needed to effectively reduce leakage in the OLED display against defect sizes of about 1 μm x 1 μm is calculated and the calculated results are tabulated in Table 1. Also listed in Table 1 are the increase in series resistance due to the short reduction layer and the sheet resistivity of the short reduction layer. The latter values are needed to evaluate possible cross talk between pixels. Table 1
The first column lists several brightness levels in cd/m2 representing the eight bit brightness resolution; the second column lists the operating current density of the OLED device at these levels; the third column lists the equivalent device resistance values of an OLED pixel at these levels; the fourth column lists the resistance of the shorting defects with the SRL in place if the leakage current is 10% of the operating current, these resistance values are ten times of the corresponding values in column three; column five lists the corresponding through-thickness resistivity of the SRL, these values are obtained by multiplying the values of column four by the area of the shorting defects which in this calculation equals to 10 cm ; column six lists the bulk resistivity values needed to achieve the corresponding through-thickness resistivity values in column five with the assumed SRL thickness of 20 nm used in this example; column seven lists the series resistance added by the SRL to the OLED device; and column eight lists the sheet resistivity of the SRL, if the sheet resistivity is comparable to the equivalent resistance of the device, cross-talk will become a problem. Table 1 shows that a SRL with 10 ohm-cm2 through-thickness resistivity can reduce leakage currents to below 10% level for the OLED down to about 100 cd/cm2 brightness level. The leakage current through SRL of this resistivity becomes a larger fraction of device current at lower brightness, however, and at the lowest brightness it can be as high as 50% of the device current. Since this is at lower brightness, it may not be a problem for many applications. The leakage current decreases as the resistivity of SRL increases. At about 160 ohm-cm2 the leakage is less than 10% of device current down to the lowest operating conditions of 6.25 cd/cm . 160 ohm-cm is also the level above which series resistance due to SRL becomes a significant fraction of the equivalent resistance of the OLED device at the full brightness. Under the set of conditions considered in Example 1, therefore, short reduction layers with through-thickness resistivity between about 10 ohm-cm to about 160 ohm-cm can be used. Note that even with through-thickness resistivity at 10 ohm-cm2 the sheet resistivity of the SRL is much larger than the equivalent device resistance. Cross-talk due to the short reduction layer is therefore not a concern. Example 2 Example 2 examines the effect of defect size on the selection of SRL. All the parameters used for Example 2 are the same as those in Example 1 except that the area of the shorting defects was varied. Table 2 shows the calculated results on how much SRL through-thickness resistivity is needed to significantly reduce leakage and how much through-thickness SRL resistivity is expected to significantly increase the series resistance of the device. Table 2
The first column lists the total defect area in cm ; the second column lists the through-thickness resistivity value that a SRL needs to have to reduce leakage current to less than 10% at 100 cd/m2 brightness level; the third column lists the through-thickness resistivity of SRL above which significant series resistance is added to the OLED device. Table 2 shows that when defect area increases, the through-thickness resistivity of the SRL increases proportionally. The through- thickness resistivity that causes significantly series resistance, however, stays constant. Table 2 demonstrates that the effectiveness of SRL increases with increasing through-thickness resistivity. It is much desirable to use SRL materials with as large a through-thickness resistivity as possible within the constrain of not adding too much series resistance. Example 3 Example 3 examines the effect of device efficiency on the selection of SRL since have been many efforts to try to improve OLED device efficiency. All4he parameters used for Example 3 are the same as those in Example 1 except that the device efficiency was varied. Table 3 shows the calculated results on how much through-thickness SRL resistivity is expected to significantly increase the series resistance of the device. Table 3
The first column lists the device efficiency in cd/A; the second column lists the through-thickness resistivity value that a SRL needs to have to reduce leakage current to less than 10% of device current at 100 cd/m2 brightness level; the third column lists the through-thickness resistivity of SRL above which significant series resistance is added to the OLED device. Table 3 shows that when device efficiency improves, the through-thickness resistivity of the SRL needed to reduce leakage to less than 10% of device current at 100 cd/m2 increases proportionally. The through-thickness resistivity that causes significantly series resistance also increases proportionally. For an OLED device with a given device efficiency a SRL film with a through-thickness resistivity value between the two values in these columns can be used to reduce the leakage without significant series resistance problem. As discussed in Example 2, however, it is desirable to use as high a through thickness resistivity value as possible in this range to increase the
effectiveness of SRL against larger size defects.
Example 4
This example examines the effect of operating voltage on the
selection of SRL. Since the operating voltage relates directly to the power
efficiency of an OLED device, there have been many efforts to try to reduce the
operating voltages. All the parameters used for Example 4 are the same as those
in Example 1 except that the operating voltage of the device was varied. Equation
3 was used to calculate how much SRL through-thickness resistivity is needed to
significantly reduce leakage and how much through-thickness SRL resistivity is
expected to significantly increase the series resistance of the device. Table 4
shows the calculated results:
Table 4
The first column lists the device operating voltage; the second column lists the
through-thickness resistivity value that a SRL needs to have to reduce leakage
current to less than 10% of device current at 100 cd/m2 brightness level; the third
column lists the through-thickness resistivity of SRL above which significant
series resistance is added to the OLED device. Table 4 shows that when device
operating voltage decreases, the through-thickness resistivity of the SRL needed
to reduce leakage to less than 10% of device current at lOOcd/m2 also decreases
proportionally. The through-thickness resistivity that causes significantly series
resistance also decreases proportionally. For an OLED device with a given
operating voltage a SRL film with a through-thickness resistivity between the two
values in these columns can be used to reduce the leakage without significant series resistance problem. As demonstrated in Example 2, however, it is desirable
to use as high a through thickness resistivity value as possible in this range to
increase the effectiveness of SRL against larger size defects.
Example 5
Example 5 examines the effect of OLED device size on the
selection of SRL. For the examples under consideration, a single pixel is the
OLED device. All the parameters used for Example 5 are the same as those in
Example 1 except that the device size was varied. Equation 3 was used to
calculate how much SRL through-thickness resistivity is needed to significantly
reduce leakage and how much through-thickness SRL resistivity is expected to
significantly increase the series resistance of the device. Table 5 shows the
calculated results:
Table 5
The first column lists the device size in cm2; the second column lists the through-
thickness resistivity value that a SRL needs to have to reduce leakage current to
less than 10% of device current at 100 cd/m2 brightness level; the third column
lists the through-thickness resistivity of SRL above which significant series
resistance is added to the OLED device. For an OLED device of a given size a
SRL film with a through-thickness resistivity between the two values in these
columns can be used to reduce the leakage without significant series resistance
problem. As demonstrated in Example 2, however, it is desirable to use as high a
through thickness resistivity value as possible in this range to increase the
effectiveness of SRL against larger size defects. Table 5 shows that the smaller the device or pixel size the higher is the through-thickness resistivity of SRL needed for leakage reduction. Example 6 Example 6 examines the short reduction layer design for an OLED device having one or more large light emitting segments. For the present application a large light emitting segment is one having an area of 0.1 cm2 or larger. One example of such device is a large area passive matrix OLED device having pixel sizes of 0.1 cm2 or larger. Another example is an OLED lighting or illumination devices having a subdivided monolithic serial connection structure as described in U.S. Patent No. 6,693,296 wherein the light emitting segments are 0.1 cm2 or larger. Usually these devices are operated only over a limited range of luminance levels. Equation 3 applies equally well to these OLED devices and suggests very different requirements of through-thickness resistivity values from those needed for high resolution displays. In this example an OLED device with large light emitting segments for illumination applications is examined. To be competitive with the commercially available compact florescent lamps, the OLED device needs to have a power efficiency of about 40 ImAV operating at about 2000 cd/m2. This kind of high power efficiency level is most likely achieved through a drive voltage reduction and an increase in the current efficiency. If the drive voltage is reduced to 3 volts, close to the theoretical limit for a white light emitting device, the current efficiency of the device needs to be about 40 cd/A since OLED devices are near Lambertian in their emission patterns. If we again allow 10% leakage loss due to shorting defects of about 10"8 cm2 total area, the resistivity requirements of a 20 nm thickness short reduction layer can be calculated and the results are tabulated in Table 6.
The first column lists the size of the light emitting segments that might be used in this OLED illumination device; the second lists the equivalent device resistance values of a light emitting segment in this OLED device; the third column lists the resistance of the shorting defects with the SRL in place if the leakage current is 10% of the operating current, these values are ten times of the corresponding values in column two; column four lists the corresponding through-thickness resistivity of the SRL, these values are obtained by multiplying the values of column three by the area of the shorting defects which in this calculation equals to 10" cm ; column five lists the bulk resistivity values needed to achieve the corresponding through-thickness resistivity values in column four with the assumed SRL thickness of 20 nm used in this example; column six lists the series resistance added by the SRL to the OLED light emitting segment; and column seven lists the maximum through-thickness resistivity value allowed for the given light emitting segment size if the serial resistance contribution from the SLR is limited to 10% of the equivalent series resistance of the light emitting segment; column eight lists the sheet resistivity of the SRL, if the sheet resistivity is comparable to the equivalent resistance of the device cross-talk will become a problem. Tuning to the row showing the results for a 1 cm2 light emitting segment as an illustration, the calculation shows that to limit the leakage current to less than 10% of the light emitting segment operating current, the short reduction layer needs only to have a through-thickness resistivity of at about 6 x 10"5 ohm- cm2 corresponding to a bulk resistivity value of about 6 ohm-cm. Higher resistivity values offer more protection against shorting defects but add more to the series resistance of the OLED light emitting segment. The value in column 7, however, shows that through-thickness resistivity as high as 60 ohm-cm2 can be used without adding significant series resistance to the OLED light emitting segment. This broad range makes it easier to find or develop short reduction layer materials that may have to satisfy many other requirements for making a practical OLED device. It is important to point out that the incorporation of charge injection layer 280 in the device structure in accordance with the present invention further simplifies the search or development of short reduction materials. Table 6 demonstrates clearly the strong dependence of resistivity requirement on light emitting segment size. For a 10 cm2 light emitting segment, the useable range of through-thickness resistivity is reduced to 6 x 10"6 to 6 x 10" 'ohm-cm2; and for a 100 cm2 light emitting segment this range is reduced further to 6 x 10"7 to 6 x 10"3 ohm-cm2. The above examples show that for high resolution displays the through thickness resistivity range needs to be in the range of about 10 -1600 ohm-cm2, and most preferably, 10 - 1000 ohm-cm2. For OLED devices with large light emitting segments the usable range is much larger, from 10'7 to 103 ohm-cm2 for the range of operating parameters considered in Example 6, but may have values outside of this range with other set of operating parameters. The selection of appropriate through-thickness resitivity values can be easily calculated, however, using Equation 3. For OLED displays or devices wherein the short reduction layer is in the path of the emitted light, the layer needs to be reasonably transparent to the emitted light to effectively to function effectively as a short reduction layer. For the purpose of the present application, reasonably transparent is defined as having 80% or more transmittance integrated over the emission bandwidth of the OLED device. If the short reduction layer is not in the path of the emitted light then it does not have to be transparent. It may even be desirable to have the short reduction layer also function as an antireflection layer for the reflecting anode or cathode to improve the contrast of an OLED display device. Material for the short reduction layer can include inorganic oxides such as indium oxide, gallium oxide, zinc oxide, tin oxide, molybdenum oxide, vanadium oxide, antimony oxide, bismuth oxide, rhenium oxide, tantalum oxide, tungsten oxide, niobium oxide, or nickel oxide. These oxides are electrically conductive because of non-stoichiometry. The resistivity of these materials depends on the degree of non-stoichiometry and mobility. These properties as well as optical transparency can be controlled by changing deposition conditions. The range of achievable resistivity and optical transparency can be further extended by impurity doping. For example F doping of tin-oxide and indium- oxide and Al, In, or Ga doping of zinc-oxide have been found to improve the conductivity and optical transparency of these oxide. Even larger range of properties can be obtained by mixing two or more of these oxides. For example, mixtures of indium oxide and tin oxide, indium oxide and zinc oxide, zinc oxide and tin oxide, or cadmium oxide and tin oxide have been the most commonly used transparent conductors. Most of the prior art has been focusing on high conductivity transparent conductors having bulk resistivity values of 10" ohm-cm or less. These materials are too conductive to be used as short reduction layers. High resistivity thin-films have also been demonstrated using these oxides for applications such as gas sensors, antistatic coatings, etc. however. Higher resistivity thin-films can be prepared by changing the composition and deposition conditions away from those optimized for high conductivity transparent conductors. Higher resistivity can also be achieved in particular using materials containing molybdenum oxide, vanadium oxide, antimony oxide, bismuth oxide rhenium oxide, tantalum oxide, tungsten oxide, niobium oxide, or nickel oxide. By properly controlling deposition conditions and by combing these oxides and mixing with the more conductive oxides such as indium oxide, gallium oxide, zinc oxide, tin oxide, etc. a wide range of resistivity values can be obtained to cover the needs for both OLED device with large light emitting segments and high resolution OLED display devices. Other materials suitable for use as short reduction layers include mixtures of a higher conductivity oxide material with an insulating materials selected from oxides, fluorides, nitrides, and sulfidess. The resistivity of the mixture layer can be tuned to the desired range by adjusting the ratio of these two kinds of materials. For example, Pal et al. ( A.M. Pal, A.J. Adorjan, P.D. Hambourger, J. A Dever, H. Fu American Physics Society, OFM96 conference abstracts CE.07) reported thin films made of a mixture of ITO with magnesium fluoride (MgF2) covering a resistivity range of 3 x 10"5 to 3 x 103 ohms-cm. These mixed thin films can be prepared by conventional thin film deposition techniques such as sputtering, evaporation, chemical vapor deposition, plasma enhanced chemical vapor deposition, etc. For the oxide films, oxygen or oxygen containing gases such as water vapor or ozone can be introduced during the deposition process to control the composition and film properties. Minami (MRS Bulletin August 2000) gave an extensive review of the preparation and properties of conductive oxides. The author showed that most of the oxide materials above work functions between about 4.0 eV and 5.0 eV. These values are too low to function as hole injectors and too high to function as electron injectors. In cases where the selected short reduction layer material does not provide adequate charge injection the present invention applies an additional hole injection layer between the short reduction layer and the organic EL element if the first electrode is the anode and an additional electron injection layer between the short reduction layer and the organic EL element if the first electrode layer is the cathode. By adding the charge injection layer, the choice of materials for short reduction layer is expanded and it is possible to further refine the selection based on other additional requirements. Suitable materials for use as the hole-injection layer include, but are not limited to, porphyrinic compounds as described in commonly assigned U.S. Patent No. 4,720,432, and plasma-deposited fluorocarbon polymers as described in commonly assigned U.S. Patent No. 6,208,075. Alternative hole-injection materials reportedly useful in organic EL devices are described in EP 0 891 121 Al and EP 1 029 909 Al and by Tokito et al. J. Phys. D. Vol. 29, p2750, 1996 including vanadium oxide (VOx), molybdenum oxide (MoOx), nickel oxide (NiOx), etc. Electron-injection layers including those taught in U.S. Patent Nos. 5,608,287; 5,776,622; 5,776,623; 6,137,223; and 6,140,763, the disclosures of which are here incorporated by reference, can be employed. A thin-film containing low work- function alkaline metals or alkaline earth metals, such as Li, Cs, Ca or Mg can be employed. In addition, an organic material doped with these low work-function metals can also be used effectively as the electron-injection layer. Examples are Li- or Cs-doped AIq. In another embodiment of the present invention, the short reduction layer is disposed between the organic EL element and the second electrode layer. The short reduction effectiveness of this embodiment is similar to the embodiment wherein the short reduction layer is disposed between the organic EL element and the first electrode layer. The short reduction effectiveness can be further improved by employing a short reduction layer both between the organic EL element and the first electrode and between the organic EL element and the second electrode. In another embodiment of the present invention, the OLED device is a stacked OLED device as described in U.S. Patent No. 6,337,492. Referring to FIG. 3, OLED device 300 is a stacked OLED device. Over a substrate 310 there are three organic light emitting devices 331 , 332, 333 each respectively including a hole transport layer (331c, 332c, 333c) light emitting layer (331b, 332b, and 333b) and an electron transport layer (331a, 332a, 333a). In between the organic light emitting devices there are the connectors 371 and 372 that provide hole to the hole transport layers above them and electrons to the electron transport layers below them. In FIG. 3 short reduction layer 360 is shown disposed between the organic light emitting device 331 and connector 371, it can also be disposed between first electrode layer 320 and organic light emitting device 331; between connecter 371 and organic light emitting device 332; between organic light emitting device 332 and connecter 372; between connecter 372 and organic light emitting device 333; and between organic light emitting device 333 and second electrode layer 340. One or more short reduction layer can be used in accordance with the present invention. Again, in accordance with the present invention, a charge injection layer is advantageous if the chosen short reduction layer does not provide adequate charge injection. In another embodiment of the present invention, the OLED device has a microcavity structure. The device includes a substrate; a metallic first anode layer, preferably selected from Au, Ag, Mg, or Ca, or alloys thereof; a short reduction layer; an organic EL element; and a metallic second electrode layer, preferably selected from Au, Al, Ag, Mg, or Ca, or alloys thereof. One of the metallic electrodes is essentially opaque and reflective, the other one is semitransparent. Because of the presence of the two reflecting metal electrodes, the device has a microcavity structure. The strong optical interference in this structure results in a resonance condition. Emission near the resonance wavelength is enhanced and emission away from the resonance wavelength is depressed. It is to be noted that although inorganic layers have been used in the prior art between an electrode layer and the organic EL element, the possibility of shorting defect reduction was not recognized and the spacer layers used were either too conductive or not transparent enough to function effectively as short reductions layers. For example, Tokito et al (S. Tokito, K. Noda, and Y. Taga J. Phys. D. Appl. Phys. 29 (1996) 2750-2753) reported using 30 nm sputtered thin- films of VOx, MoOx, and RuOx as hole injectors. These films were disposed in the path of the emitted light and yet the optical transparency of all these thin-films were 70% or less and the resistivity of the latter two films were much too low to function effectively as short reduction layers. Example 7 A series of OLED devices were made on ITO coated glass substrates. The ITO anode layers were about 42 nm thick; deposited over the ITO layer were a short reduction layer (SRL), a 15 nm N,N'-di(naphthalene-l-yl) - N,N'-diphenyl-benzidine (NPB) layer serving as the HTL layer, a 15 nm tris(8- hydroxyquinoline)aluminum(III) (AIq) layer serving both as the ETL and the LEL; a 1 nm thick Li layer serving as the EIL, and a 100 nm thick Ag serving as the cathode layer. All the layers except ITO, which was purchased from a vendor already coated on the glass, were coated by vacuum evaporation in a chamber with a background vacuum of about 10~6 torr. Thermally evaporated MoO3 layer was used as the SRL. These M0O3 layers were evaporated from a Ta boat at a rate of about 0.1 nm/sec with a thickness ranging from 2 nm to 30 nm. The source material was 99.9998% MoO3 powder. The composition of the films were not checked and it could deviated somewhat from the MoO3 composition. The films were transparent to the visible light with about 90% transmittance and the electrical resistivity was about 105 ohms-cm. After the deposition of these layers, the device was transferred from the deposition chamber into a dry box for encapsulation. The completed device structure is denoted as Glass/ITO(42)/Mo03(varied)/NPB(15)/Alq(l 5)/Li(0.1 )/Ag(l 00). The numbers in the parentheses are thickness in nanometers. Altogether 12 substrates were coated, two at each MoO3 thickness. On each substrate there were four 0.1 cm2 OLED devices with a total of eight OLED devices at each MoO3 thickness. There were a total of 48 OLED devices for this study. These devices were tested for OLED performance. Seven out of eight devices with 2 nm MoO3 layer were shorted as expected since the total organic thickness of 30 nm is so thin that the devices were extremely prone to shorting defects and 2 nm OfMoO3 did not function adequately as a short reduction layer. The number of shorted devices decreased with increasing MoO3 thickness. Only four out of thirty devices were shorted when the thickness of the MoO3 layer was 12 nm or higher. These results are summarized in FIG.5. It is to be pointed out, however, that the probability of having shorting defects in an OLED device is a strong function of the organic EL layer thickness. The smaller the organic EL layer thickness the higher the probability of having shorting defects. Typical OLED devices use organic EL layers that are over 100 nm in thickness. Frequently the thickness of the organic EL element is increased to 300 nm or higher in order to minimum the number of shorting defects. In the present example an extremely small thickness of 30 nm was used to make sure that we had adequate number of shorting defects to demonstrate the effectiveness of the short reduction layers. Data in FIG. 4 demonstrated that the short reduction was effective in reducing shorting defects in these OLED devices with extremely thin organic EL layers. The same beneficial effect is expected in OLED devices with much thicker organic EL layers. Example 8 Another series of OLED devices were made to further demonstrate the effectiveness of the short reduction layers. The fabrication condition and the layer structure of these devices were similar to those in Example 1 except that in this example the total thickness of the MoO3 short reduction layer and the NPB HTL layer was kept constant at 75 nm. Five substrates were used with four OLED devices on each substrate resulted in a total of twenty 0.1 cm OLED devices being made. In FIG. 5 the number of non-shorted devices was plotted against the M0O3 short reduction layer thickness. Again, it is clear that the number of non-shorted devices increased with increasing MoO3 layer thickness. It is to be pointed out that in this case the thickness of the organic EL layer actually decreased with increasing MoO3 thickness, which should have increased shorting probability. The opposite trend observed in the actual data indicated that the benefit of the short reduction layer more than overcame the increased shorting probability due to reduced organic layer thickness. The invention has been described in detail with particular reference to certain preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the invention. Parts List 100, 200, 300 OLED devices 110, 210, 310 substrates 120, 220, 320 first electrode layers 130, 230 organic EL layers 140, 240, 340 second electrode layers 150, 250 shorting defects 260 short reduction layer 280 charge injection layer 331, 332, 333 organic light emitting devices 331 a, 332a, 333a electron transport layers 331b, 332b, 333b light emitting layers 331c, 332c, 333c hole transport layers 360 short reduction layer 371, 372 connectors
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