Title:
PHOSPHINE COMPOUND, INTERMEDIATE, PALLADIUM-COMPLEX, AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO2004072088
Kind Code:
A3
Abstract:
Palladum-phosphine complexes obtained by reacting a 5 compound of formula (1) below with a palladium compound: (wherein R<1 >is a hydrogen atom, an alkyl group, a cycloalkyl group or a phenyl group which may be substituted; R<2> and R<3> are each, the same or different, an alkyl group, a cycloalkyl group or a phenyl group which may be substituted; R<4> and R<5> are each, the same or different, a hydrogen atom, an alkyl group, a cycloalkyl group or a phenyl group which may be substituted; R<6>, R<7>, R<8> and R<9> are each, the same or different, an alkyl group, a cycloalkyl group, a phenyl group which may be substituted, an alkoxyl group, a dialkylamino group, a halogen atom, a phenyl group, a benzyl group, a naphthyl group or a halogenated alkyl group; R<6> and R<7>, R<8> and R<9> may be combined to form, each, a fused ring, a trimethylene group, a tetramethylene group or a 20 methylenedioxy group; p, q, r and s are each an integer of 0 to 5; and p + q, and r + s are each in the range of 0 to 5.), which is a novel and efficient catalyst for manufacturing various useful compounds.
Inventors:
SUZUKI KEN (JP)
HORI YOJI (JP)
HORI YOJI (JP)
Application Number:
PCT/JP2004/001514
Publication Date:
September 23, 2004
Filing Date:
February 12, 2004
Export Citation:
Assignee:
TAKASAGO PERFUMERY CO LTD (JP)
SUZUKI KEN (JP)
HORI YOJI (JP)
SUZUKI KEN (JP)
HORI YOJI (JP)
International Classes:
C07B37/04; C07B43/04; C07C17/269; C07C41/30; C07C213/08; C07F9/50; C07F15/00; C07C217/92; (IPC1-7): C07F9/50; C07F15/00; C07C23/04; C07B37/00
Other References:
TOPOLSKI, M. ET AL: "Chiral carbenoids: their formation and reactions", JOURNAL OF ORGANIC CHEMISTRY (1993), 58(3), 546-55, 1993, XP002279592
WALBORSKY, H. M. ET AL: "Carbenoids. Metal assisted ionization", TETRAHEDRON LETTERS (1985), 26(23), 2743-6, 1985, XP002279593
BOCHE, G. ET AL: "Alternative pathways in the reactions of cyclopropyl halides with alkali metal naphthalenes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1980), 102(17), 5697-9, 1980, XP002279594
LUCKENBACH, REINER ET AL: "Electrocyclic ring opening of cyclopropyl halides in the course of their reaction with sodium iodide in acetone", ZEITSCHRIFT FUER NATURFORSCHUNG, TEIL B: ANORGANISCHE CHEMIE, ORGANISCHE CHEMIE (1979), 34B(3), 464-80, 1979, XP008030602
SANDER, VOLKER ET AL: "Synthesis and reactions of 1-chloro-1-cyclopropanecarboxylic acids and 1-cyclopropene-1-carboxylic acids", CHEMISCHE BERICHTE (1978), 111(12), 3879-91, 1978, XP008030603
WALBORSKY, H. M. ET AL: "Cyclopropanes. XXXIII. Reaction of lithium metal surfaces with opticall active 1-halo-1-methyl-2,2-diphenylcyclopropane", JOURNAL OF ORGANOMETALLIC CHEMISTRY (1973), 51, 55-75, 1973, XP002279597
WALBORSKY, H. M. ET AL: "Cyclopropanes. XXXII. Mechanism of Grignard formation", JOURNAL OF ORGANOMETALLIC CHEMISTRY (1973), 51, 31-53, 1973, XP002279598
WALBORSKY, HARRY M. ET AL: "Cyclopropanes. XXIX. Stereochemistry of the 1-methyl-2,2- diphenylcyclopropyl radical in and out of solvent cage", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1971), 93(3), 671-5, 1971, XP002279599
HAUSSER, JACK W. ET AL: "Solvolysis of cyclopropyl halides. 2-Phenylcyclopropyl chlorides", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1967), 89(26), 6981-4, 1967, XP002279600
IKEDA, HIROSHI ET AL: "Spectroscopic and Calorimetric Studies on the Mechanism of Methylenecyclopropane Rearrangements Triggered by Photoinduced Electron Transfer", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003), 125(30), 9147-9157, 2003, XP002279601
WALBORSKY, H. M. ET AL: "Carbenoids. Metal assisted ionization", TETRAHEDRON LETTERS (1985), 26(23), 2743-6, 1985, XP002279593
BOCHE, G. ET AL: "Alternative pathways in the reactions of cyclopropyl halides with alkali metal naphthalenes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1980), 102(17), 5697-9, 1980, XP002279594
LUCKENBACH, REINER ET AL: "Electrocyclic ring opening of cyclopropyl halides in the course of their reaction with sodium iodide in acetone", ZEITSCHRIFT FUER NATURFORSCHUNG, TEIL B: ANORGANISCHE CHEMIE, ORGANISCHE CHEMIE (1979), 34B(3), 464-80, 1979, XP008030602
SANDER, VOLKER ET AL: "Synthesis and reactions of 1-chloro-1-cyclopropanecarboxylic acids and 1-cyclopropene-1-carboxylic acids", CHEMISCHE BERICHTE (1978), 111(12), 3879-91, 1978, XP008030603
WALBORSKY, H. M. ET AL: "Cyclopropanes. XXXIII. Reaction of lithium metal surfaces with opticall active 1-halo-1-methyl-2,2-diphenylcyclopropane", JOURNAL OF ORGANOMETALLIC CHEMISTRY (1973), 51, 55-75, 1973, XP002279597
WALBORSKY, H. M. ET AL: "Cyclopropanes. XXXII. Mechanism of Grignard formation", JOURNAL OF ORGANOMETALLIC CHEMISTRY (1973), 51, 31-53, 1973, XP002279598
WALBORSKY, HARRY M. ET AL: "Cyclopropanes. XXIX. Stereochemistry of the 1-methyl-2,2- diphenylcyclopropyl radical in and out of solvent cage", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1971), 93(3), 671-5, 1971, XP002279599
HAUSSER, JACK W. ET AL: "Solvolysis of cyclopropyl halides. 2-Phenylcyclopropyl chlorides", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1967), 89(26), 6981-4, 1967, XP002279600
IKEDA, HIROSHI ET AL: "Spectroscopic and Calorimetric Studies on the Mechanism of Methylenecyclopropane Rearrangements Triggered by Photoinduced Electron Transfer", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003), 125(30), 9147-9157, 2003, XP002279601
Download PDF: