Title:
POLYMERISATION CATALYSTS WITH TRIAZENIDO LIGANDS
Document Type and Number:
WIPO Patent Application WO2004063233
Kind Code:
A3
Abstract:
A polymerisation catalyst comprising (1) a nitrogen-containing transition metal compound of Formula (A), and (2) an organoaluminium or hydrocarbylboron activator, wherein either (a) R<1> and R<2> are monovalent groups or (b) R<1> and R<2 >integrally form a divalent group R<3> bridging the terminal nitrogen atoms of the triazene unit via carbon atoms; R<1> and R<2> and the divalent group R<3> are (i) aliphatic hydrocarbon, (ii) alicyclic hydrocarbon, (iii) aromatic hydrocarbon, (iv) alkyl substituted aromatic hydrocarbon (v) heterocyclic groups and (vi) heterosubstituted derivatives of said groups (i) to (v); M is a metal from Group 3 to 11 of the Periodic Table or a lanthanide metal; X is an anionic group, L is a neutral donor group; n is 1 or 2, y and z are independently zero or integers such that the number of X and L groups satisfy the valencyand oxidation state of the metal M. The catalyst is used to polymerise 1-olefins especially ethylene and propylene. High molecular weight homo- and co-polypropylene are disclosed.
Inventors:
GIBSON VERNON CHARLES (GB)
REARDON DAMIEN FRANCIS (CA)
TOMOV ATANAS KOSTADINOV (GB)
REARDON DAMIEN FRANCIS (CA)
TOMOV ATANAS KOSTADINOV (GB)
Application Number:
PCT/GB2004/000109
Publication Date:
August 18, 2005
Filing Date:
January 09, 2004
Export Citation:
Assignee:
INNOVENE EUROP LTD (GB)
GIBSON VERNON CHARLES (GB)
REARDON DAMIEN FRANCIS (CA)
TOMOV ATANAS KOSTADINOV (GB)
GIBSON VERNON CHARLES (GB)
REARDON DAMIEN FRANCIS (CA)
TOMOV ATANAS KOSTADINOV (GB)
International Classes:
C07F7/00; C07F15/04; C08F4/642; C08F4/70; C08F4/80; C08F10/00; C08F110/02; C08F110/06; (IPC1-7): C08F10/00; C08F4/642; C08F4/70; C08F4/80; C07F7/00; C07F15/00
Domestic Patent References:
| WO1999005186A1 | 1999-02-04 | |||
| WO2000012568A1 | 2000-03-09 | |||
| WO2001055227A2 | 2001-08-02 |
Other References:
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KAMEDA, NORIYUKI ET AL KAMEDA, NORIYUKI ET AL: "Polymerization of vinyl monomers with a dihydridorhodium complex-tetrahydrofuran system Polymerization of vinyl monomers with a dihydridorhodium complex-tetrahydrofuran system", XP002277773, retrieved from STN Database accession no. 1985:46319
GOMEZ, MONTSERRAT ET AL: "Synthesis and characterization of triazenido and amidino complexes of nickel and palladium", POLYHEDRON , 12(10), 1171-7 CODEN: PLYHDE; ISSN: 0277-5387, 1993, XP001188972
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KAMEDA, TOKUYUKI: "Dihydrido(1,3-diphenyltriazenido)[bis(1,2- diphenylphosphino)benzene]rhodium", XP002277774, retrieved from STN Database accession no. 1989:423725
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KAMEDA, NORIYUKI ET AL KAMEDA, NORIYUKI ET AL: "Polymerization of methyl methacrylate with a dihydridorhodium complex-tetrahydrofuran system Polymerization of methyl methacrylate with a dihydridorhodium complex-tetrahydrofuran system", XP002277775, retrieved from STN Database accession no. 1985:578692
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KAMEDA, NORIYUKI ET AL KAMEDA, NORIYUKI ET AL: "Polymerization of methyl methacrylate initiated by the dihydridorhodium complex-carbon tetrachloride system Polymerization of methyl methacrylate initiated by the dihydridorhodium complex-carbon tetrachloride system", XP002277776, retrieved from STN Database accession no. 1983:523010
WALTHER, D. ET AL: "Organozirconium chemistry with inorganic donor ligands N,N'-bis(trimethylsilyl)benzamidinate (Siam) in compounds of type (Siam)2ZrX2 (X = methyl, benzyl, allyl, chloride oder iodide) and (Siam)3ZrX (X = chloride)", JOURNAL OF ORGANOMETALLIC CHEMISTRY , 508(1-2), 13-22 CODEN: JORCAI; ISSN: 0022-328X, 1996, XP004206125
GUZEI, ILIA A. ET AL: "Synthesis and characterization of titanium and zirconium complexes bearing diphenyltriazenido ligands", POLYHEDRON , 16(23), 4017-4022 CODEN: PLYHDE; ISSN: 0277-5387, 1997, XP001188975
CHIU, KWOK W. ET AL: "Interaction of organic azides with methyl compounds of cobalt, rhodium, iridium, ruthenium and zirconium to give azido or 1,3-triazenido complexes. The crystal structures of tris(trimethylphosphine)azidodimethylcobalt(III) and bis(carbonyl)trimethylphosphineazidocobalt(I)", POLYHEDRON , 3(1), 79-85 CODEN: PLYHDE; ISSN: 0277-5387, 1984, XP001188973
HILLHOUSE, GREGORY L. ET AL: "Monosubstituted triazenido complexes as intermediates in the formation of amido complexes from hafnium hydrides and aryl azides", ORGANOMETALLICS , 1(8), 1025-9 CODEN: ORGND7; ISSN: 0276-7333, 1982, XP001188974
BRINCKMAN, F. E. ET AL: "Metal-nitrogen bonding. Covalent complexes of 1,3-dimethyltriazene with elements of Groups I, II, III, IV, and V", INORG. CHEM. , 4(7), 936-42, 1965, XP001188971
SANCHEZ, GREGORIO ET AL: "Organonickel(II) complexes with anionic N-donor ligands. Hydration of coordinated nitriles at a nickel(II) site", HELVETICA CHIMICA ACTA , 80(8), 2477-2485 CODEN: HCACAV; ISSN: 0018-019X, 1997, XP001161194
MAJUMDAR, A. K. ET AL: "Coordination complexes of copper(II), nickel(II), cobalt(II), and cobaltnIII) with p-substituted 1,3-diphenyltriazene", JOURNAL OF THE INDIAN CHEMICAL SOCIETY , 50(11), 697-700 CODEN: JICSAH; ISSN: 0019-4522, 1973, XP008030147
PENG, SHIE MING ET AL: "Structure of triazenido complexes cis-bis(pyridine)bis(1,3- diphenyltriazenido)cobalt(II) and nickel(II)", BULLETIN OF THE INSTITUTE OF CHEMISTRY, ACADEMIA SINICA , 32, 1-8 CODEN: BICMAD; ISSN: 0366-0370, 1985, XP008030148
RUIZ, JOSE ET AL: "Synthesis and characterization of chelate and bridging triazenide complexes of palladium and platinum. Stereoselective oxidative addition of chlorine or iodine to [NBu4][Pt(C6F5)2(.eta.2-PhNNNPh)]", JOURNAL OF THE CHEMICAL SOCIETY, DALTON TRANSACTIONS , (18), 2683-2689 CODEN: JCSDAA; ISSN: 1472-7773, 2001, XP001190862
GOMEZ, MONTSERRAT ET AL: "Synthesis and characterization of triazenido and amidino complexes of nickel and palladium", POLYHEDRON , 12(10), 1171-7 CODEN: PLYHDE; ISSN: 0277-5387, 1993, XP001188972
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KAMEDA, TOKUYUKI: "Dihydrido(1,3-diphenyltriazenido)[bis(1,2- diphenylphosphino)benzene]rhodium", XP002277774, retrieved from STN Database accession no. 1989:423725
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KAMEDA, NORIYUKI ET AL KAMEDA, NORIYUKI ET AL: "Polymerization of methyl methacrylate with a dihydridorhodium complex-tetrahydrofuran system Polymerization of methyl methacrylate with a dihydridorhodium complex-tetrahydrofuran system", XP002277775, retrieved from STN Database accession no. 1985:578692
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KAMEDA, NORIYUKI ET AL KAMEDA, NORIYUKI ET AL: "Polymerization of methyl methacrylate initiated by the dihydridorhodium complex-carbon tetrachloride system Polymerization of methyl methacrylate initiated by the dihydridorhodium complex-carbon tetrachloride system", XP002277776, retrieved from STN Database accession no. 1983:523010
WALTHER, D. ET AL: "Organozirconium chemistry with inorganic donor ligands N,N'-bis(trimethylsilyl)benzamidinate (Siam) in compounds of type (Siam)2ZrX2 (X = methyl, benzyl, allyl, chloride oder iodide) and (Siam)3ZrX (X = chloride)", JOURNAL OF ORGANOMETALLIC CHEMISTRY , 508(1-2), 13-22 CODEN: JORCAI; ISSN: 0022-328X, 1996, XP004206125
GUZEI, ILIA A. ET AL: "Synthesis and characterization of titanium and zirconium complexes bearing diphenyltriazenido ligands", POLYHEDRON , 16(23), 4017-4022 CODEN: PLYHDE; ISSN: 0277-5387, 1997, XP001188975
CHIU, KWOK W. ET AL: "Interaction of organic azides with methyl compounds of cobalt, rhodium, iridium, ruthenium and zirconium to give azido or 1,3-triazenido complexes. The crystal structures of tris(trimethylphosphine)azidodimethylcobalt(III) and bis(carbonyl)trimethylphosphineazidocobalt(I)", POLYHEDRON , 3(1), 79-85 CODEN: PLYHDE; ISSN: 0277-5387, 1984, XP001188973
HILLHOUSE, GREGORY L. ET AL: "Monosubstituted triazenido complexes as intermediates in the formation of amido complexes from hafnium hydrides and aryl azides", ORGANOMETALLICS , 1(8), 1025-9 CODEN: ORGND7; ISSN: 0276-7333, 1982, XP001188974
BRINCKMAN, F. E. ET AL: "Metal-nitrogen bonding. Covalent complexes of 1,3-dimethyltriazene with elements of Groups I, II, III, IV, and V", INORG. CHEM. , 4(7), 936-42, 1965, XP001188971
SANCHEZ, GREGORIO ET AL: "Organonickel(II) complexes with anionic N-donor ligands. Hydration of coordinated nitriles at a nickel(II) site", HELVETICA CHIMICA ACTA , 80(8), 2477-2485 CODEN: HCACAV; ISSN: 0018-019X, 1997, XP001161194
MAJUMDAR, A. K. ET AL: "Coordination complexes of copper(II), nickel(II), cobalt(II), and cobaltnIII) with p-substituted 1,3-diphenyltriazene", JOURNAL OF THE INDIAN CHEMICAL SOCIETY , 50(11), 697-700 CODEN: JICSAH; ISSN: 0019-4522, 1973, XP008030147
PENG, SHIE MING ET AL: "Structure of triazenido complexes cis-bis(pyridine)bis(1,3- diphenyltriazenido)cobalt(II) and nickel(II)", BULLETIN OF THE INSTITUTE OF CHEMISTRY, ACADEMIA SINICA , 32, 1-8 CODEN: BICMAD; ISSN: 0366-0370, 1985, XP008030148
RUIZ, JOSE ET AL: "Synthesis and characterization of chelate and bridging triazenide complexes of palladium and platinum. Stereoselective oxidative addition of chlorine or iodine to [NBu4][Pt(C6F5)2(.eta.2-PhNNNPh)]", JOURNAL OF THE CHEMICAL SOCIETY, DALTON TRANSACTIONS , (18), 2683-2689 CODEN: JCSDAA; ISSN: 1472-7773, 2001, XP001190862
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