Title:
POLYTHIOPHENE CONJUGATED POLYMER CONTAINING ELECTRON-WITHDRAWING SUBSTITUENT, PREPARATION METHOD THEREFOR AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2022/151675
Kind Code:
A1
Abstract:
A polythiophene conjugated polymer containing an electron-withdrawing substituent, a preparation method therefor, and the use thereof. The structural formula of the polymer is as represented by formula I. The preparation method comprises: under the protection of an inert atmosphere, dissolving a dibromo monomer, a bis-trialkyltin monomer, a palladium catalyst and a ligand in an organic solvent; and carrying out a Stille polymerization reaction under the conditions of darkness and heating to reflux, so as to obtain a polythiophene conjugated polymer containing an electron-withdrawing substituent. Further provided is the use of the polythiophene conjugated polymer, which contains the electron-withdrawing substituent and is represented by formula I, in an organic field effect transistor as an electron transport material, and the use of the polythiophene conjugated polymer as an n-type high-molecular thermoelectric material.
Inventors:
LIU JUN (CN)
MENG BIN (CN)
DENG SIHUI (CN)
WANG LIXIANG (CN)
MENG BIN (CN)
DENG SIHUI (CN)
WANG LIXIANG (CN)
Application Number:
PCT/CN2021/104930
Publication Date:
July 21, 2022
Filing Date:
July 07, 2021
Export Citation:
Assignee:
CHANGCHUN INST APPLIED CHEMISTRY CAS (CN)
International Classes:
C08G61/12; H01L35/24; H01L51/05; H01L51/30
Domestic Patent References:
| WO2018076247A1 | 2018-05-03 |
Foreign References:
| CN112940228A | 2021-06-11 | |||
| CN111961030A | 2020-11-20 | |||
| CN111518074A | 2020-08-11 | |||
| CN102317345A | 2012-01-11 |
Other References:
ZHANG SHIQIAN; QIAO XIAOLAN; XIONG YU; WU QINGHE; LIU ZHIQIANG; LI HONGXIANG; FANG QI: "Bi-thieno[3,4]pyrrole-4,6-dione based copolymers: 1,2-Bis(2-thienyl)ethene unit vs 1,2-diphenylethene unit", ORGANIC ELECTRONICS, ELSEVIER, AMSTERDAM, NL, vol. 56, 10 February 2018 (2018-02-10), AMSTERDAM, NL, pages 146 - 151, XP085365357, ISSN: 1566-1199, DOI: 10.1016/j.orgel.2018.02.011
Attorney, Agent or Firm:
CHINA SCIENCE PATENT & TRADEMARK AGENT LTD. (CN)
Download PDF:
Previous Patent: METHOD FOR MEASURING SELF-REFRESH FREQUENCY
Next Patent: CHIP STRUCTURE, PACKAGING STRUCTURE AND FABRICATION METHOD THEREFOR
Next Patent: CHIP STRUCTURE, PACKAGING STRUCTURE AND FABRICATION METHOD THEREFOR