Title:
POROUS METAL COMPLEX, METHOD FOR PRODUCING POLYMER USING SAME, AND VINYL ESTER COPOLYMER
Document Type and Number:
WIPO Patent Application WO/2014/123091
Kind Code:
A1
Abstract:
The object of the invention is to provide a method for producing a polymer having high solvent resistance and to provide a vinyl ester copolymer having high solvent resistance. Provided as a means for attaining the above object are: a method for producing a polymer, characterized in that a monomer (V) having unsaturated double bonds is polymerized in the pores of a porous metal complex containing an aromatic polycarboxylic acid compound (L1) having at least two substituents that have terminal alkenyl groups, and containing at least one type of metal ion selected from ions of metals belonging to groups 1-14 of the periodic table, and a polymer containing the aromatic polycarboxylic acid compound (L1) in the monomer units is obtained; and a vinyl ester copolymer with the aromatic compound (L1) having at least two substituents that have terminal alkenyl groups, the copolymer being characterized in that a polymer chain containing the vinyl ester monomer in the main chain is crosslinked by the aromatic compound (L1) and oriented in one dimension.
Inventors:
UEMURA TAKASHI (JP)
KITAGAWA SUSUMU (JP)
KONISHI HIROYUKI (JP)
INUBUSHI YASUTAKA (JP)
FUKUMOTO TAKASHI (JP)
KITAGAWA SUSUMU (JP)
KONISHI HIROYUKI (JP)
INUBUSHI YASUTAKA (JP)
FUKUMOTO TAKASHI (JP)
Application Number:
PCT/JP2014/052468
Publication Date:
August 14, 2014
Filing Date:
February 03, 2014
Export Citation:
Assignee:
UNIV KYOTO (JP)
International Classes:
C08F218/04; C01B31/02; C07C63/28; C07C65/38; C08F8/12; C08F212/08; C08F216/06; C08F220/14; C07F1/08; C07F3/06
Foreign References:
| JP2012530718A | 2012-12-06 | |||
| JP2009143786A | 2009-07-02 | |||
| JP2010159228A | 2010-07-22 | |||
| JP2012527995A | 2012-11-12 |
Other References:
GAETANO DISTEFANO ET AL.: "Highly ordered alignment of a vinyl polymer by host-guest cross-polymerization", NATURE CHEMISTRY, vol. 5, no. 4, April 2013 (2013-04-01), pages 335 - 341
RYO NAKANISHI ET AL.: "Kakyogata Takoshitsu Kinzoku Sakutai o Mochiita Kobunshi no Haiko Seigyo Gosei", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, vol. 93, no. 2, 8 March 2013 (2013-03-08), pages 240
JESSE G.MCDANIEL ET AL.: "Microscopic Origins of Enhanced Gas Adsorption and Selectivity in Mixed-Linker Metal-Organic Frameworks", THE JOURNAL OF PHYSICAL CHEMISTRY C, vol. 117, no. 33, 22 August 2013 (2013-08-22), pages 17131 - 17142
LIAN-XU SHI ET AL.: "The roles of the allyloxy groups on terephthalate for the formation of three coordination networks", INORGANIC CHEMISTRY COMMUNICATIONS, vol. 14, no. 4, April 2011 (2011-04-01), pages 569 - 572
MIN KIM ET AL.: "Functional tolerance in an isoreticular series of highly porous metal- organic frameworks", DALTON TRANSACTIONS, vol. 41, no. 20, 28 May 2012 (2012-05-28), pages 6277 - 6282
TAKASHI UEMURA ET AL.: "Functionalization of Coordination Nanochannels for Controlling Tacticity in Radical Vinyl Polymerization", J. AM. CHEM. SOC., vol. 132, no. 13, 2010, pages 4917 - 4924
RYO NAKANISHI ET AL.: "Kakyogata Takoshitsu Kinzoku Sakutai o Mochiita Kobunshi no Haiko Seigyo Gosei", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, vol. 93, no. 2, 8 March 2013 (2013-03-08), pages 240
JESSE G.MCDANIEL ET AL.: "Microscopic Origins of Enhanced Gas Adsorption and Selectivity in Mixed-Linker Metal-Organic Frameworks", THE JOURNAL OF PHYSICAL CHEMISTRY C, vol. 117, no. 33, 22 August 2013 (2013-08-22), pages 17131 - 17142
LIAN-XU SHI ET AL.: "The roles of the allyloxy groups on terephthalate for the formation of three coordination networks", INORGANIC CHEMISTRY COMMUNICATIONS, vol. 14, no. 4, April 2011 (2011-04-01), pages 569 - 572
MIN KIM ET AL.: "Functional tolerance in an isoreticular series of highly porous metal- organic frameworks", DALTON TRANSACTIONS, vol. 41, no. 20, 28 May 2012 (2012-05-28), pages 6277 - 6282
TAKASHI UEMURA ET AL.: "Functionalization of Coordination Nanochannels for Controlling Tacticity in Radical Vinyl Polymerization", J. AM. CHEM. SOC., vol. 132, no. 13, 2010, pages 4917 - 4924
Attorney, Agent or Firm:
SAEGUSA & PARTNERS (JP)
Patent business corporation 3 Edakuni [Hajime] patent firm (JP)
Patent business corporation 3 Edakuni [Hajime] patent firm (JP)
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