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Title:
PROCESS FOR OPERATING THE EPOXIDATION OF ETHYLENE
Document Type and Number:
WIPO Patent Application WO2001096324
Kind Code:
A3
Abstract:
A process for the vapor phase oxidation of ethylene to ethylene oxide, which process comprises reacting a reaction mixture comprising ethylene and oxygen in the presence of a supported highly selective silver-based catalyst by: operating at an initial operation phase wherein fresh catalyst is used, and operating at a further operation phase when a cumulative ethylene oxide production exceeds 0.01 kT ethylene oxide per m<3> of catalyst, wherein in said further operation phase the concentration of ethylene in the reaction mixture is increased; and a method of using ethylene oxide for making 1,2-ethanediol or a corresponding 1,2-ethanediol ether comprising converting the ethylene oxide into the 1,2-ethanediol or the 1,2-ethanediol ether wherein the ethylene oxide has been obtained by the process for the production of ethylene oxide.

Inventors:
EVANS WAYNE ERROL (US)
CHIPMAN PETER INGRAHAM (US)
Application Number:
PCT/US2001/018097
Publication Date:
March 28, 2002
Filing Date:
June 05, 2001
Export Citation:
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Assignee:
SHELL OIL CO (US)
EVANS WAYNE ERROL (US)
CHIPMAN PETER INGRAHAM (US)
International Classes:
C07D301/08; B01J23/68; C07B61/00; C07C29/10; C07C31/20; C07C41/02; C07C43/13; C07D301/10; C07D303/04; (IPC1-7): C07D301/10; B01J23/68; C07C29/10
Foreign References:
EP0266015A11988-05-04
GB1319004A1973-05-31
EP0625370A11994-11-23
US5545603A1996-08-13
EP0567273A11993-10-27
US5380697A1995-01-10
EP0557833A11993-09-01
US4400559A1983-08-23
DE19843697A12000-03-30
US3935279A1976-01-27
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