Title:
PYROPHOSPHORIC ACID ESTER COMPOUND, BISPHOSPHORIC ACID ESTER COMPOUND, AND CATALYST
Document Type and Number:
WIPO Patent Application WO/2014/014035
Kind Code:
A1
Abstract:
The invention pertains to a novel pyrophosphoric acid ester compound represented by formula (1) and a bisphosphoric acid ester compound represented by formula (2). In the formulas, R is an aryl group, organic silyl group, or halogen atom. These compounds can adequately activate carbonyl compounds, imine compounds, and the like due to having higher acidity than conventional phosphoric acid ester compounds. Usefulness as a metal ligand is also expected.
Inventors:
ISHIHARA KAZUAKI (JP)
SAKAKURA AKIRA (JP)
SAKAKURA AKIRA (JP)
Application Number:
PCT/JP2013/069443
Publication Date:
January 23, 2014
Filing Date:
July 17, 2013
Export Citation:
Assignee:
UNIV NAGOYA NAT UNIV CORP (JP)
International Classes:
C07F9/12; B01J31/02; C07F9/6574; C07F19/00; C07B61/00; C07C29/56; C07C35/17; C07C231/14; C07C233/73; C07C269/06; C07C271/20; C07F7/08
Domestic Patent References:
| WO2011111677A1 | 2011-09-15 | |||
| WO2007114445A1 | 2007-10-11 | |||
| WO2004096753A1 | 2004-11-11 |
Foreign References:
| JP2006035125A | 2006-02-09 | |||
| JPS5069090A | 1975-06-09 |
Other References:
RYO OKAMOTO ET AL.: "Synthesis of Chiral Binaphthyl Pyrophospate and Development to Chiral Bronsted Acid Catalysts", 93RD ANNUAL MEETING OF THE CHEMICAL SOCIETY OF JAPAN IN SPRING (2013) KOEN YOKOSHU IV, 8 March 2013 (2013-03-08), pages 1365
TAKAHIRO HORIBE ET AL.: "Chiral Dai Ichi, Ni Zoku Kinzoku Binaphtholate Shokubai o Mochiiru Aldimine eno Chokusetsuteki Fusei Mannich-gata Hanno Oyobi a, beta-Fuhowa Ketone eno Fusei Hydrophosphonyl-ka Hanno", DAI 101 KAI SYMPOSIUM ON ORGANIC SYSTHESIS, 30 May 2012 (2012-05-30), JAPAN YOSHISHU, pages 81 - 84
RYOTA USAMI ET AL.: "Chiral Cho Bunshi Shokubai o Mochiiru a-Chikan Acrolein ni Taisuru Ijo na Ko End Sentakuteki Fusei Diels-Alder Hanno", 91ST ANNUAL MEETING OF THE CHEMICAL SOCIETY OF JAPAN IN SPRING (2011) KOEN YOKOSHU IV, 2011, pages 1252
TAKAHIRO HORIBE ET AL.: "Chiral Dai Ichi, Ni Zoku Kinzoku Binaphtholate Shokubai o Mochiiru Aldimine eno Chokusetsuteki Fusei Mannich-gata Hanno Oyobi a, beta-Fuhowa Ketone eno Fusei Hydrophosphonyl-ka Hanno", DAI 101 KAI SYMPOSIUM ON ORGANIC SYSTHESIS, 30 May 2012 (2012-05-30), JAPAN YOSHISHU, pages 81 - 84
RYOTA USAMI ET AL.: "Chiral Cho Bunshi Shokubai o Mochiiru a-Chikan Acrolein ni Taisuru Ijo na Ko End Sentakuteki Fusei Diels-Alder Hanno", 91ST ANNUAL MEETING OF THE CHEMICAL SOCIETY OF JAPAN IN SPRING (2011) KOEN YOKOSHU IV, 2011, pages 1252
Attorney, Agent or Firm:
ITEC INTERNATIONAL PATENT FIRM (JP)
Patent business corporation Itec international patent firm (JP)
Patent business corporation Itec international patent firm (JP)
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