Title:
STAR-SHAPED MOLECULE CAPABLE OF BEING USED FOR HOLE TRANSPORT LAYER, PREPARATION METHOD THEREFOR, AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2024/031993
Kind Code:
A1
Abstract:
The present invention provides a star-shaped molecule capable of being used for a hole transport layer, a preparation method therefor, and use thereof. The star-shaped molecule capable of being used for the hole transport layer has a structure represented by formula I. The present invention provides a star-shaped molecule capable of being used for a hole transport layer, a preparation method therefor, and use thereof. The star-shaped molecule capable of being used for the hole transport layer has a structure represented by formula I.
The star-shaped molecule provided by the present invention has a branched structure. A triphenylamine molecule with a pyramid-shaped conformation is at the tail end of the molecule. Triphenylamine and benzothiadiazole, the central core of the molecule, are connected by means of a carbon-carbon triple bond. The benzothiadiazole unit in the molecule has a substituent group. The star-shaped molecule has the characteristics of both high hole mobility and easy solution processing, and can be used in perovskite solar cells, and can effectively improve the luminous efficiency of the cells.
Inventors:
ZHANG YUN (CN)
ZHAO ZHIGUO (CN)
ZHAO DONGMING (CN)
LI XINLIAN (CN)
XIA YUAN (CN)
QIN XIAOJUN (CN)
LIU JIALIANG (CN)
LIANG SICHAO (CN)
ZHAO ZHIGUO (CN)
ZHAO DONGMING (CN)
LI XINLIAN (CN)
XIA YUAN (CN)
QIN XIAOJUN (CN)
LIU JIALIANG (CN)
LIANG SICHAO (CN)
Application Number:
PCT/CN2023/082965
Publication Date:
February 15, 2024
Filing Date:
March 22, 2023
Export Citation:
Assignee:
HUANENG CLEAN ENERGY RES INST (CN)
International Classes:
C07D285/14; C09K11/06; H01L31/0216
Foreign References:
| CN115028602A | 2022-09-09 | |||
| CN101348537A | 2009-01-21 | |||
| CN103073541A | 2013-05-01 |
Other References:
YAN LINYIN, CHEN XUDONG, HE QINGGUO, WANG YINGYING, WANG XUEFEI, GUO QIANJIN, BAI FENGLIAN, XIA ANDONG, AUMILER DAMIR, VDOVIĆ SILV: "Localized Emitting State and Energy Transfer Properties of Quadrupolar Chromophores and (Multi)Branched Derivatives", THE JOURNAL OF PHYSICAL CHEMISTRY A, WASHINGTON DC, US, vol. 116, no. 34, 30 August 2012 (2012-08-30), US , pages 8693 - 8705, XP093139006, ISSN: 1089-5639, DOI: 10.1021/jp305407s
BALASARAVANAN RAJENDIRAN, SADHASIVAM VELU, SIVA AYYANAR, PANDI MOHAN, THANASEKARAN GANESAN, ARULVASU CHINNASAMY: "Synthesis, Characterization and Photophysical Studies of D-π-A Based Conjugated Triphenylamine Derivatives", CHEMISTRYSELECT, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 1, no. 11, 16 July 2016 (2016-07-16), DE , pages 2792 - 2801, XP093139012, ISSN: 2365-6549, DOI: 10.1002/slct.201600608
HE CHANG, HE QINGGUO, YI YUANPING, WU GUANGLONG, BAI FENGLIAN, SHUAI ZHIGANG, LI YONGFANG: "Improving the efficiency of solution processable organic photovoltaic devices by a star-shaped molecular geometry", JOURNAL OF MATERIALS CHEMISTRY, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 18, no. 34, 1 January 2008 (2008-01-01), GB , pages 4085, XP093139014, ISSN: 0959-9428, DOI: 10.1039/b807456a
ZHANG BONG JUNE, JEON SEUNG-JOON: "Two-photon properties of bis-1,4-(p-diarylaminostyryl)-2,5-dicyanobenzene derivatives: two-photon cross-section tendency in multi-branched structures", CHEMICAL PHYSICS LETTERS, ELSEVIER BV, NL, vol. 377, no. 1-2, 24 July 2003 (2003-07-24), NL , pages 210 - 216, XP093139016, ISSN: 0009-2614, DOI: 10.1016/S0009-2614(03)01129-1
BALASARAVANAN RAJENDIRAN, SADHASIVAM VELU, SIVA AYYANAR, PANDI MOHAN, THANASEKARAN GANESAN, ARULVASU CHINNASAMY: "Synthesis, Characterization and Photophysical Studies of D-π-A Based Conjugated Triphenylamine Derivatives", CHEMISTRYSELECT, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 1, no. 11, 16 July 2016 (2016-07-16), DE , pages 2792 - 2801, XP093139012, ISSN: 2365-6549, DOI: 10.1002/slct.201600608
HE CHANG, HE QINGGUO, YI YUANPING, WU GUANGLONG, BAI FENGLIAN, SHUAI ZHIGANG, LI YONGFANG: "Improving the efficiency of solution processable organic photovoltaic devices by a star-shaped molecular geometry", JOURNAL OF MATERIALS CHEMISTRY, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 18, no. 34, 1 January 2008 (2008-01-01), GB , pages 4085, XP093139014, ISSN: 0959-9428, DOI: 10.1039/b807456a
ZHANG BONG JUNE, JEON SEUNG-JOON: "Two-photon properties of bis-1,4-(p-diarylaminostyryl)-2,5-dicyanobenzene derivatives: two-photon cross-section tendency in multi-branched structures", CHEMICAL PHYSICS LETTERS, ELSEVIER BV, NL, vol. 377, no. 1-2, 24 July 2003 (2003-07-24), NL , pages 210 - 216, XP093139016, ISSN: 0009-2614, DOI: 10.1016/S0009-2614(03)01129-1
Attorney, Agent or Firm:
UNITALEN ATTORNEYS AT LAW CO., LTD. (CN)
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