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Patent Searching and Data


Title:
PRODUCTION OF CYCLOOLEFIN POLYMER
Document Type and Number:
Japanese Patent JPH08165309
Kind Code:
A
Abstract:

PURPOSE: To produce a cycloolefin polymer having excellent mechanical properties, excellent heat resistance, a high molecular weight and a narrow molecular weight distribution by bringing a cycloolefin monomer into contact with a catalyst comprising an organic transition metal compound and an organoaluminumoxy compound.

CONSTITUTION: A cycloolefin monomer is brought into contact with a catalyst comprising an organic transition metal compound of formula I and an organoaluminumoxy compound comprising a structural units of formula II and b structural units of formula III in a b/(a+b) of 0.10-0.90. In the formulas, Cp is cyclopentadienyl or the like; A is halogeno or the like; M is a group 4 or 5 transition metal in the periodic table; m is the valence of the metal M; R2 is a 2-10C hydrocarbon resmdue; R3 to R14 are each H or the like; K is 0 or 1; and n≥1.


Inventors:
NISHIZAWA OSAMU
TAKASAKI KENJI
ARITOMI MITSUTOSHI
Application Number:
JP30924294A
Publication Date:
June 25, 1996
Filing Date:
December 13, 1994
Export Citation:
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Assignee:
MITSUBISHI CHEM CORP
International Classes:
C08F4/642; C08F4/60; C08F4/6592; C08F32/00; C08F32/04; (IPC1-7): C08F4/642; C08F32/04
Attorney, Agent or Firm:
Kazuo Sato (2 outside)