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Title:
SCALING PREVENTING METHOD IN WET LIME GYPSUM METHOD DESULFURIZATION APPARATUS OR DESULFURIZATION AND DENITRATION APPARATUS
Document Type and Number:
Japanese Patent JPS5462970
Kind Code:
A
Abstract:

PURPOSE: To prevent scaling in the title apparatus by circulating part of a gypsum free filtrate leaving a gypsum separating process to a cooling and dust removing process and maintaining the concn. of Cl- in the cooling and dust removing process to below a specific value.

CONSTITUTION: Exhaust gas 1 is fed to dust removing and cooling tower 2 to remove dust such as carbon and supplied to absorption tower 3 as stad. wet gas of 55W60°C. Lime slurry 4 is introduced into tower 3 to be reacted with SOx in the gas, forming CaSO3. This CaSO3-contg. absorbing liquid is fed to oxidation tower 5 to convert the CaSO3 into gypsum. The gypsum-contg. oxidized liquid is then fed to gypsum separator 6 to separate product gypsum 7. The filtrate is returned to lime preparation vessel 7, and at the same time part of the filtrate is circulated to tower 2. A chlorine-contg. inorg. salt such as NaCl is added to the filtrate circulated to tower 2, and above 1000, esp. 5000W8000 ppm of Cl- is introduced into the absorbing liquid fed to tower 2. Thus, scaling can be prevented esp. in the piping of tower 2.


Inventors:
KANAMARU KIYOSHI
TSUGAWA HIROTSUGU
MATSUO KATSUHIKO
KOJIMA SUNAO
FUKADA YOSHINOBU
Application Number:
JP13011477A
Publication Date:
May 21, 1979
Filing Date:
October 29, 1977
Export Citation:
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Assignee:
ISHIKAWAJIMA HARIMA HEAVY IND
International Classes:
B01D53/50; B01D53/14; B01D53/34; B01D53/60; B01D53/77; C01F11/46; C23F14/02; (IPC1-7): B01D53/14; B01D53/34; C01F11/46; C23F14/02
Domestic Patent References:
JPS50136283A1975-10-29
JPS493874A1974-01-14
JPS5015784A1975-02-19
JPS5033994A1975-04-02