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Title:
SUSPENSION POLYMERIZATION OF VINYL CHLORIDE-BASED RESIN
Document Type and Number:
Japanese Patent JPH10338702
Kind Code:
A
Abstract:

To provide a suspension polymerization method for a vinyl chloride- based resin, free from adhesion of resin scale on the inner wall of a polymerizer, providing a vinyl chloride-based resin composition having a sharp particle size distribution and a bulk specific gravity, almost no skin layer part on the surface of the particles and extremely excellent moldability and processability.

This method for subjecting a vinyl chloride-based monomer to suspension polymerization in the presence of an oil-soluble polymerization initiator in an aqueous medium. A partially saponified polyvinyl acetate (a) having 60-80 mol.% saponification degree, 450-600 average polymerization degree and 3-10 cP viscosity (viscosity of 4 wt.% solution in a solvent of water/ methanol of 1/1 (weight ratio) and a measured value by a Brookfield viscometer at 20°C based on JIS K 6,726), at least one emulsifying agent (b) of a sorbitan higher fatty acid ester having 3-10 cP HLB value and an anionic emulsifying agent, a 8-25C higher fatty acid (c) and a water-soluble thicker (d) having 10-200 cP Brookfield viscosity at 0.1% aqueous solution at normal temperature under normal pressure are added to the reaction system.


Inventors:
ASAHINA KENICHI
SHIBAZAKI YUKIO
Application Number:
JP15115797A
Publication Date:
December 22, 1998
Filing Date:
June 09, 1997
Export Citation:
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Assignee:
SEKISUI CHEMICAL CO LTD
International Classes:
C08F2/20; C08F2/44; C08F14/00; C08F14/06; (IPC1-7): C08F2/20; C08F2/44; C08F14/06