Title:
ORGANIC METAL COMPLEX CATALYST FOR OLEFIN METATHESIS REACTION
Document Type and Number:
WIPO Patent Application WO/2023/048084
Kind Code:
A1
Abstract:
The present invention provides an organic metal complex catalyst for an olefin metathesis reaction, which enables the achievement of a higher yield of a desired substance in an olefin metathesis reaction than the conventional catalysts. The organic metal complex catalyst according to the present invention has a structure represented by formula (1) and is used for an olefin metathesis reaction. In formula (1), M represents a coordination center and is an Ru atom or an ion thereof; R1, R2 and R3 may be the same as or different from each other and independently represent a substituent such as a hydrogen atom; R4, R5, R6 and R7 may be the same as or different from one another and independently represent a substituent such as a hydrogen atom; X represents a halogen atom; and R8 represents a substituent having 3 to 20 carbon atoms and having a π bond.
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Inventors:
CHOI JUNCHUL (JP)
FUKAYA NORIHISA (JP)
MATSUMOTO KAZUHIRO (JP)
MIZUSAKI TOMOTERU (JP)
TAKAGI YUKIO (JP)
SEKI YASUHIRO (JP)
FUKAYA NORIHISA (JP)
MATSUMOTO KAZUHIRO (JP)
MIZUSAKI TOMOTERU (JP)
TAKAGI YUKIO (JP)
SEKI YASUHIRO (JP)
Application Number:
PCT/JP2022/034764
Publication Date:
March 30, 2023
Filing Date:
September 16, 2022
Export Citation:
Assignee:
N E CHEMCAT CORP (JP)
AIST (JP)
AIST (JP)
International Classes:
B01J31/24; C07B61/00; C07C1/207; C07C11/04; C07C67/475; C07C69/74; C07F7/10; C07F9/6506; C07F15/00; C07F19/00
Domestic Patent References:
| WO2011069134A2 | 2011-06-09 | |||
| WO2021177000A1 | 2021-09-10 | |||
| WO2018105671A1 | 2018-06-14 | |||
| WO2018105672A1 | 2018-06-14 |
Foreign References:
| JP2007501814A | 2007-02-01 | |||
| JP2016509006A | 2016-03-24 | |||
| JPH11262667A | 1999-09-28 | |||
| JP2003500412A | 2003-01-07 | |||
| JP2002524250A | 2002-08-06 |
Other References:
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P. SCHWAB ET AL., ANGEW. CHEM., INT. ED., vol. 34, 1995, pages 2039
JAFARPOUR, L.STEVENS, E. D.NOLAN, S. P., J. ORGANOMET. CHEM., vol. 606, 2000, pages 49 - 54
M. SCHOLL ET AL., ORG. LETT., vol. 1, 1999, pages 953
T. DROGEF. GLORIUS, ANGEW. CHEM. INT. ED., vol. 49, 2010, pages 6940
WANG, Y.XIE, YAMING.ABRAHAM, M. Y.WEI, P.SCHAEFER III, H. F.SCHLEYER, P. R.ROBINSON, G. H., J. AM. CHEM. SOC., vol. 132, 2010, pages 14370
TANG, P.WANG, W.RITTER, T., J. AM. CHEM. SOC., vol. 133, 2011, pages 11482
POMPEO, M.FROESE, R. D. J.HADEI, N.ORGAN, M. G., ANGEW. CHEM. INT. ED., vol. 51, 2012, pages 11354
P. SCHWAB ET AL., ANGEW. CHEM., INT. ED., vol. 34, 1995, pages 2039
JAFARPOUR, L.STEVENS, E. D.NOLAN, S. P., J. ORGANOMET. CHEM., vol. 606, 2000, pages 49 - 54
M. SCHOLL ET AL., ORG. LETT., vol. 1, 1999, pages 953
T. DROGEF. GLORIUS, ANGEW. CHEM. INT. ED., vol. 49, 2010, pages 6940
WANG, Y.XIE, YAMING.ABRAHAM, M. Y.WEI, P.SCHAEFER III, H. F.SCHLEYER, P. R.ROBINSON, G. H., J. AM. CHEM. SOC., vol. 132, 2010, pages 14370
TANG, P.WANG, W.RITTER, T., J. AM. CHEM. SOC., vol. 133, 2011, pages 11482
POMPEO, M.FROESE, R. D. J.HADEI, N.ORGAN, M. G., ANGEW. CHEM. INT. ED., vol. 51, 2012, pages 11354
Attorney, Agent or Firm:
IPR CONSULTANT PPC (JP)
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