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Title:
Z-TYPE SOLANONE, PREPARATION METHOD THEREFOR, AND USE
Document Type and Number:
WIPO Patent Application WO/2021/068530
Kind Code:
A1
Abstract:
Disclosed is a Z-type solanone, the three-dimensional structural formula thereof being (I) or (II), and the name thereof being: (S,Z)-5-isopropyl-8-methyl-6,8-dien-2-one, or (R,Z)-5-isopropyl-8-methyl-6,8-dien-2-one. Also disclosed are a preparation method for the Z-type solanone, and a use in cigarette tobacco flavouring.

Inventors:
LEI SHENG (CN)
LIU ZHIHUA (CN)
WANG KAI (CN)
LI ZHENJIE (CN)
MAO DESHOU (CN)
WANG KUNMIAO (CN)
GAO LI (CN)
FU LEI (CN)
ZHANG YIPENG (CN)
ZHE WEI (CN)
YANG YING (CN)
ZHOU QIANGHUI (CN)
Application Number:
PCT/CN2020/093673
Publication Date:
April 15, 2021
Filing Date:
June 01, 2020
Export Citation:
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Assignee:
CHINA TOBACCO YUNNAN IND CO LTD (CN)
International Classes:
C07C45/68; A24B3/12; A24B15/32; C07C49/203
Foreign References:
CN111004104A2020-04-14
CN105367517A2016-03-02
US4433695A1984-02-28
US3174485A1965-03-23
SE370489B1974-10-21
Other References:
DEMOLE EDOUARD, DEMOLE CÉCILE: "A Chemical Study ofBurley Tobacco Flavour (Nicotiana tabacum L.) VII. Identification and synthesis of twelve irregular terpenoids, related to solanone, including 7,8-dioxabicyclo[3.2.1]octane and 4,9-dioxabicyclo[3.3.1]nonane derivatives", HELVETICA CHIMICA ACTA, VERLAG HELVETICA CHIMICA ACTA., vol. 58, no. 7, 5 November 1975 (1975-11-05), pages 1867 - 1880, XP055798782, ISSN: 0018-019X, DOI: 10.1002/hlca.19750580702
DATABASE STN REGISTRY STN REGISTRY; ANONYMOUS: "6,8-Nonadien-2-one, 8-methyl-5-(1-methylethyl)-, [R-(Z)]- (9CI) (CA INDEX NAME)", XP055798791, retrieved from STN REGISTRY
DATABASE REGISTRY 16 November 1984 (1984-11-16), ANONYMOUS: "6,8-Nonadien-2-one, 8-methyl-5-(1-methylethyl)-, (Z)- (9CI) (CA INDEX NAME)", XP055862400, retrieved from STN Database accession no. 90940-44-6
JOHNSON ROBERT R, NICHOLSON JOHN A: "The Structure, Chemistry, and Synthesis of Solanone. A New Anomalous Terpenoid Ketone from Tobacco1", JOURNAL OF ORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, vol. 30, no. 9, 1 September 1965 (1965-09-01), Washington, pages 2918 - 2921, XP055798784, ISSN: 0022-3263, DOI: 10.1021/jo01020a009
See also references of EP 3954675A4
Attorney, Agent or Firm:
BEIJING LINGZHUAN INTELLECTUAL PROPERTY AGENCY CO., LTD (CN)
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